Citation: YANG Ying-Li, YAN Xin-Long, HU Xiao-Yan, ZHOU Min. Zn/Al Hydrotalcite with Different n_Zn/n_Al Molar Ratios:Synthesis and Phthalic Acid Adsorption Behaviour[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1748-1756. doi: 10.11862/CJIC.2017.232 shu

Zn/Al Hydrotalcite with Different n_Zn/n_Al Molar Ratios:Synthesis and Phthalic Acid Adsorption Behaviour

School of Chemical Engineering & Technology, Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: YAN Xin-Long, yanxl@cumt.edu.cn
Received Date: 12 April 2017
Revised Date: 30 August 2017

Figures(10)

Zn-Al layered double hydroxides (LDHs) with different Zn/Al molar ratios were prepare by co-preci-pitation method in this work. The structure and composition were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), thermogravimetric (TG), N₂ adsorption-desorption and inductively coupled plasma mass spectrometry (ICP-MS). The adsorption properties of as-prepared Zn/Al hydrotalcites for phthalic acid removal from water were investigated and compared. Results show that the adsorption capacity increased with the increasing of Zn/Al molar ratios at low Zn/Al molar ratios for hydrotalcites. Further increasing the n_Zn/n_Al molar ratios (>6), the adsorption capacity shows little change. Among those hydrotalcites, one sample with the highest adsorption capacity was selected and its adsorption kinetic and isotherm was further investigated. The adsorption equilibrium data were well described by Freundlich isotherm model and the kinetics followed a pseudo-second order kinetic equation/mechanism. In addition, the hydrotalcite can be reused at least 3 cycles without significant loss of adsorption capacity.
- hydrotalcite,
- Zn/Al molar ratios,
- adsorption and separation,
- phthalic acid,
- adsorption kinetics,
- adsorption thermodynamics
1. [1]
  Charles A S, Dennis R P, Thomas F P, et al. Chemosphere, 1997, 35(4):667-749 doi: 10.1016/S0045-6535(97)00195-1
2. [2]
  Susanne J, Jörgen E, Anna L, et al. Water Res., 2003, 37:609-617 doi: 10.1016/S0043-1354(02)00304-4
3. [3]
  Mahmoud M, JoséR U, Raúl O P, et al. J. Environ. Manage., 2012, 109:164-178 doi: 10.1016/j.jenvman.2012.05.014
4. [4]
  CHEN Bo, LIN JiAn-Guo, CHEN Qing, Envirinmental Science and Management, 2009, 34(2):71-75
5. [5]
  NafaâA, Lotfi M. Sep. Purif. Technol., 2004, 38:233-239 doi: 10.1016/j.seppur.2003.11.011
6. [6]
  JoséD M D, Mahmoud M A D, JoséR U, et al. J. Colloid Interface Sci., 2012, 369:358-365 doi: 10.1016/j.jcis.2011.11.073
7. [7]
  CHENG Xu-Ze, WU Jia-Wei, QIU Cai-Ying, et al. Chemistry & Bioengineering, 2016, 33(1):57-59
8. [8]
  LI Xiao-Juan, HE Chang-Fa, HUANG Bin, et al. Chemical Industry and Engineering Progress, 2016, 35(2):586-594
9. [9]
  Chan H W, Lau T C, Ang P O, et al. J. Appl. Phycol., 2004, 16:263-274 doi: 10.1023/B:JAPH.0000047778.93467.af
10. [10]
  Markéta J, Roman S. J. Environ. Manage., 2012, 94:13-24 doi: 10.1016/j.jenvman.2011.09.006
11. [11]
  Ayranci E, Bayram E. J. Hazard. Mater., 2005, 122:147-153 doi: 10.1016/j.jhazmat.2005.03.022
12. [12]
  Li J D, Shi Y L, Cai Y Q, et al. Chem. Eng. J., 2008, 140:214-220 doi: 10.1016/j.cej.2007.09.037
13. [13]
  Yan X L, Yang Y L, Wang C, et al. J. Sol-Gel Sci. Technol., 2016, 60:523-530
14. [14]
  Wang C, Yan X L, Hu X Y, et al. J. Mol. Liq., 2016, 223:427-430 doi: 10.1016/j.molliq.2016.08.056
15. [15]
  Richetta M, Digiamberardino L, Mattoccia A, et al. Surf. Interface Anal., 2016, 48:514-518 doi: 10.1002/sia.v48.7
16. [16]
  Liu J Q, Song J Y, Xiao H D, et al. Powder Technol., 2014, 253:41-45 doi: 10.1016/j.powtec.2013.11.007
17. [17]
  Kloprogge J T, Hickey L, Frost R L. J. Solid State Chem., 2004, 177:4047-4057 doi: 10.1016/j.jssc.2004.07.010
18. [18]
  Mascolo G, Mascolo M C. Microporous Mesoporous Mater., 2015, 214:246-248 doi: 10.1016/j.micromeso.2015.03.024
19. [19]
  Peligro F R, Pavlovic I, Rojas R, et al. Chem. Eng. J., 2016, 306:1035-1040 doi: 10.1016/j.cej.2016.08.054
20. [20]
  Inacio J, Taviot-Gueho C, Forano C, et al. Appl. Clay Sci., 2001, 18:255-264 doi: 10.1016/S0169-1317(01)00029-1
21. [21]
  ZHANG Lu-Hong, TANG You-Gen, ZHANG Li, et al. Journal of Functional Materials, 2012, 18(43):2469-2472
22. [22]
  WANG Long, GAO Xu, GUO Jin-Song, et al. Journal of Chongqing University, 2011, 5(11):2537-2541
23. [23]
  Li F, Wang Y F, Yang Q Z, et al. J. Hazard. Mater., 2005, 125(1/2/3):89-95
24. [24]
  Frederick L T, Godwin A A, Ray L F. Appl. Surf. Sci., 2016, 383:200-213 doi: 10.1016/j.apsusc.2016.04.150
25. [25]
  Li R H, Wang J J, Zhou B Y, et al. Sci. Total Environ., 2016, 559:121-129 doi: 10.1016/j.scitotenv.2016.03.151
26. [26]
  Tzompantzi F, Mantilla A, Baňuelos F, et al. Top. Catal., 2011, 54:257-263 doi: 10.1007/s11244-011-9656-3
27. [27]
  Abdullah A A A, Abidin Z T, Mohd Z B H, et al. J. Solid State Chem., 2012, 191:271-278 doi: 10.1016/j.jssc.2012.03.013
28. [28]
  Seftel E M, Popovici E, Mertens M, et al. Microporous Mesoporous Mater., 2008, 113:296-304 doi: 10.1016/j.micromeso.2007.11.029
29. [29]
  Kingshuk D, Somnath D, Amitava P. J. Colloid Interface Sci., 2012, 366:8-36 doi: 10.1016/j.jcis.2011.09.065
30. [30]
  Huang J H, Yang Z H, Wang R J, et al. J. Mater. Chem. A, 2015, 3:7429-7436 doi: 10.1039/C5TA00279F
31. [31]
  SONG Guo-Jun, SUN Linag-Dong, LI Pei-Yao, et al. Materials Review, 2008, 22(1):53-57
32. [32]
  Didier T, Olivier L, Bernard C, et al. Microporous Mesoporous Mater., 2005, 80:213-220 doi: 10.1016/j.micromeso.2004.12.015
33. [33]
  Tatjana V, Andreas R, Jonjaua R, et al. J. Therm. Anal. Calorim., 2012, 110:227-233 doi: 10.1007/s10973-012-2230-9
34. [34]
  WANG Lan, GE Sheng-Song, SHAO Qian, et al. Chinese J. Inorg. Chem., 2016, 32(11):1896-1904
35. [35]
  Benito P, Labajos F M, Rocha J, et al. Microporous Mesoporous Mater., 2006, 94:148-158 doi: 10.1016/j.micromeso.2006.03.038
36. [36]
  Nazmul A K, Beom K J, Zubair H, et al. J. Hazard. Mater., 2015, 282:194-200 doi: 10.1016/j.jhazmat.2014.03.047
37. [37]
  LIU Zong-Tang, SUN Yu-Feng, YANG Shang-Shang, et al. Ion Exchange and Adsorption, 2013, 29(1):51-57
38. [38]
  Shahwan T. J. Environ. Chem. Eng., 2014, 2:1001-1006 doi: 10.1016/j.jece.2014.03.020
39. [39]
  Ho Y S, McKay G. Process Biochem., 1999, 34:451-465 doi: 10.1016/S0032-9592(98)00112-5
40. [40]
  YUE Qin-Yan, XIE JiAn-Kun, GAO Bao-Yue, et al. Acta Scientiae Circumstantiae, 2007, 27(9):1431-1438
41. [41]
  SUN Xiao-Li, ZENG Qing-Xuan, FENG Chang-Gen. Acta Phys.-Chim. Sin., 2009, 25(10):1951-1957 doi: 10.3866/PKU.WHXB20090938
42. [42]
  WANG Long, GAO Xu, GUO Jin-Song, et al. Journal of Chongqing University, 2010, 33(7):91-96 doi: 10.11835/j.issn.1000-582X.2010.07.017
43. [43]
  SUN YuAn-Yuan, ZENG Xi-Bai, BAI Ling-Yu. Acta Scientiae Circumstantiae, 2011, 31(70):1377-1385
44. [44]
  NI Zhe-Ming, WANG Qiao-Qiao, YAO Ping. Acta Chim. Sinica, 2011, 69(5):529-535
1. [1]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
2. [2]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
5. [5]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
6. [6]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
7. [7]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
8. [8]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
9. [9]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
10. [10]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
11. [11]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
12. [12]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
13. [13]
  Guo-Hong Gao , Run-Ze Zhao , Ya-Jun Wang , Xiao Ma , Yan Li , Jian Zhang , Ji-Sen Li . Core–shell heterostructure engineering of CoP nanowires coupled NiFe LDH nanosheets for highly efficient water/seawater oxidation. Chinese Chemical Letters, 2024, 35(8): 109181-. doi: 10.1016/j.cclet.2023.109181
14. [14]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
15. [15]
  Sinong Wang , Shanshan Jin , Xue Yang , Yanyan Huang , Peng Liu , Yi Tang , Yuliang Yang . Development of Mg-Al LDH and LDO as novel protective materials for deacidification of paper-based relics. Chinese Chemical Letters, 2024, 35(9): 109890-. doi: 10.1016/j.cclet.2024.109890
16. [16]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
17. [17]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
18. [18]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
19. [19]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
20. [20]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(3914)
HTML views(816)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Zn/Al Hydrotalcite with Different nZn/nAl Molar Ratios:Synthesis and Phthalic Acid Adsorption Behaviour

Metrics

通讯作者: 陈斌, bchen63@163.com

Zn/Al Hydrotalcite with Different n_Zn/n_Al Molar Ratios:Synthesis and Phthalic Acid Adsorption Behaviour