Citation: YANG Ming-Rong, SHEN Yong, HU Xiao-Sai, ZHANG Hui-Fang, WANG Li-Ming, XU Li-Hui, XING Ya-Jun. Synthesis of Fe-CuS/RGO by Solvothermal Method with High Visible Photocatalytic Activity[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(7): 1223-1230. doi: 10.11862/CJIC.2017.148 shu

Synthesis of Fe-CuS/RGO by Solvothermal Method with High Visible Photocatalytic Activity

1.
Fashion College, Shanghai University of Engineering Science, Shanghai 201620, China
2.
Shanghai Textile Science Research Institute, Shanghai 201620, China

Corresponding author: SHEN Yong, shenyong@sues.edu.cn
Received Date: 17 February 2017
Revised Date: 11 May 2017

Figures(11)

The Fe element doped CuS/RGO (Fe-CuS/RGO) was fabricated via a facile one-step solvothermal method, which displayed outstanding photocatalytic activity for methylene blue (MB) degradation.The composition and structure of the prepared composites were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectra, photoluminescence (PL) spectra, scanning electron microscopy (SEM), Transmission electron microscope (TEM) and UV-Vis optical absorption spectroscopy.The results showed that pristine CuS, CuS/RGO and Fe-CuS/RGO exhibited photocatalytic activity for the photodegradation of MB with degradation efficiency of 41.2%, 81.5% and 90.6%, respectively, in 140 min under mercury lamp irradiation, indicating that Fe-CuS/RGO could be acknowledged as a promising photocatalyst for the removal of organic contaminants.The enhanced photocatalytic activity was ascribed to that Fe element could be acted as an interfacial charge transfer channel between CuS and RGO to thus inhibit the recombination of photogenerated electron-holes pairs.
- Fe-CuS/RGO,
- methylene blue,
- photocatalyst
1. [1]
  HU Xiao-Sai, SHEN Yong, WANG Li-Ming, et al. Aerosp. Mater. Technol., 2015, 6:1-7 doi: 10.3969/j.issn.1007-2330.2015.05.001
2. [2]
  LI Guang-Bing, HOU Zhao-Xia, WANG Shao-Hong, et al. Ordnance Mater. Sci. Eng., 2014, 37(3):122-126
3. [3]
  LIU Hui, DONG Xiao-Nan, SUN Chao-Chao. J. Shaanxi Univ. Sci. Technol., 2013, 31(1):23-28
4. [4]
  HU Xiao-Sai, SHEN Yong, WANG Li-Ming, et al. Chin. J. Carbon Tech., 2016, 2:11-17
5. [5]
  Ravichandran K, Chidhambaram N, Gobalakrishnan S. J. Phys. Chem. Solids, 2016, 93:82-90 doi: 10.1016/j.jpcs.2016.02.013
6. [6]
  Zargari S, Rahimi R, Ghaffarinejad A, et al. J. Colloid Interface Sci., 2016, 466:310-321 doi: 10.1016/j.jcis.2015.12.046
7. [7]
  Di J, Xia J, Jia M X, et al. Appl. Catal. B:Environ., 2016, 183:254-262 doi: 10.1016/j.apcatb.2015.10.036
8. [8]
  Hu X S, Shen Y, Zhang Y T, et al. J. Alloys Compd., 2017, 695:1178-1785
9. [9]
  Hu X S, Shen Y, Zhang Y T, et al. J. Phys. Chem. Solids, 2017, 103:201-208 doi: 10.1016/j.jpcs.2016.12.021
10. [10]
11. [11]
  Yu C F, Dong S Y, Zhao J, et al. J. Alloys Compd., 2016, 277:219-227
12. [12]
  Hu X S, Shen Y, Xu L H, et al. Appl. Surf. Sci., 2016, 385:162-170 doi: 10.1016/j.apsusc.2016.05.089
13. [13]
  Shi J J, Zhou X Y, Liu Y, et al. Mater. Lett., 2014, 126:220-223 doi: 10.1016/j.matlet.2014.04.051
14. [14]
  Hu X, Shen Y, Xu L H, et al. J. Alloys Compd., 2016, 674:289-294 doi: 10.1016/j.jallcom.2016.03.047
15. [15]
  Almeida N, Martins P, Teixeira S, et al. Mater. Sci., 2016, 51:6974-6986 doi: 10.1007/s10853-016-9986-4
16. [16]
  Meng N, Zhou Y, Nie W, et al. Nanopart. Res., 2015, 17:300-309 doi: 10.1007/s11051-015-3105-3
17. [17]
  Posa V, Annavaram V, Koduru J, et al. J. Chem. Eng., 2016, 33:456-464
18. [18]
  WU Xiao-Yu, LI Song-Mei, LIU Jian-Hua, et al. J. Inorg. Mater., 2014, 29(8):845-850
19. [19]
20. [20]
  TAN Zhi-Gang, ZHU Qi-An, GUO Xun-Zhi, et al. Acta Chim. Sinica, 2011, 69(23):2812-2820
21. [21]
  Li P, Chen Q, Lin Y Y, et al. J. Alloys Compd., 2016, 672:497-504 doi: 10.1016/j.jallcom.2016.02.143
22. [22]
  Zhu M S, Zhai C Y, Sun M G, et al. Appl. Catal. B:Environ., 2017, 203:108-115 doi: 10.1016/j.apcatb.2016.10.012
23. [23]
  Zhai C Y, Zhu M S, Pang F Z, et al. ACS Appl. Mater. Interfaces, 2016, 8:5972-5980 doi: 10.1021/acsami.5b10234
24. [24]
  Zou C E, Yang B B, Bin D, et al. J. Colloid Interface Sci., 2017, 488:135-141 doi: 10.1016/j.jcis.2016.10.088
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1.
沈阳化工大学材料科学与工程学院沈阳 110142