Citation: WANG Xin-Ping, LI Ying-Ying, LIU Yong, SUN Jing, LIU Kang, WANG Lei. Syntheses, Structures and Luminescence Properties of Coordination Polymers in Mixed-Ligand System[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 823-829. doi: 10.11862/CJIC.2017.104 shu

Syntheses, Structures and Luminescence Properties of Coordination Polymers in Mixed-Ligand System

College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China

Corresponding author: LIU Kang, liukang82@126.com
Received Date: 3 November 2016
Revised Date: 8 April 2017

Figures(6)

Three novel coordination polymers, formulated as[Cd₃(pic)₄(H₂bmimb)]_n (1), [Co₃(pic)₄(H₂bmimb)]_n (2), [Cd₂(1, 2-mbix)(pic)₂(H₂O)₂]_n (3) (H₂bmimb=1, 4-bis ((2-methyl-1H-imidazol-1-yl) methyl) benzene, 1, 2-mbix=1, 2-bis ((2-methyl-1H-imidazol-1-yl) methyl) benzene, pic=5-phenylisophthalic acid), were synthesized by self-assembly of mixed ligands with Cd (Ⅱ) and Co (Ⅱ) under solvothermal conditions and characterized by means of single-crystal X-ray diffraction, X-ray powder diffraction, infrared spectra, thermogravimetric analysis and fluorescence spectra. Single-crystal X-ray diffraction analysis revealed that complexes 1 and 2 possess 3D anionic frameworks, in which the protonated bis-imidazole ligands balance the charge of the frameworks. In complex 3, the Cd²⁺ ions are linked by pic and 1, 2-mbix ligands to generate a 1D chain structure. The adjacent chains are held together to form a 2D layer via π…π stacking and then a 3D supramolecular framework through hydrogen-bonding interactions. In addition, luminescence properties of complexes 1 and 3 in the solid state were characterized.
- solvothermal synthesis,
- coordination polymers,
- mixed-ligand,
- luminescence propreties
1. [1]
  Clearfield A. Prog. Inorg. Chem., 1998, 47:371-510
2. [2]
  Eddaoudi M, Moler D B, Li H, et al. Acc. Chem. Res., 2001, 34:319-330 doi: 10.1021/ar000034b
3. [3]
  Yaghi O M, O'Keeffe M, Ockwig N W, et al. Nature, 2003, 423:705-714 doi: 10.1038/nature01650
4. [4]
  Férey G, Mellot-Draznieks C, Serre C, et al. Science, 2005, 309:2040-2042 doi: 10.1126/science.1116275
5. [5]
  Kitagawa S, Kitaura R, Noro S H. Angew. Chem. Int. Ed., 2004, 43:2334-2375 doi: 10.1002/(ISSN)1521-3773
6. [6]
  Hamilton T D, Papaefstathiou G S, MacGillivray L R. J. Solid State Chem., 2005, 178:2409-2413 doi: 10.1016/j.jssc.2005.05.034
7. [7]
  Férey G, Serre C, Devic T, et al. Chem. Soc. Rev., 2011, 40:550-562 doi: 10.1039/C0CS00040J
8. [8]
  ZHOU Lian, TIE Sheng-Nian, WANG Zhi-Guo. Chinese J. Inorg. Chem., 2015, 31:1480-1488
9. [9]
  ZHONG Kai-Long, LUO Li. Chinese J. Inorg. Chem., 2016, 32:275-279
10. [10]
  HUANG Chu-Ting, WU Xiao-Feng, LI Guang-Hua, et al. Chem. J. Chinese Universities, 2015, 36:1661-1666
11. [11]
  Wang H Y, Wu Y, Leong C F, et al. Inorg. Chem., 2015, 54:10766-10775 doi: 10.1021/acs.inorgchem.5b01803
12. [12]
  Aijaz A, Saudo E C, Bharadwaj P K. Cryst. Growth Des., 2011, 11:1122-1134 doi: 10.1021/cg101351b
13. [13]
  Cao X Y, Mu B, Huang R D. CrystEngComm, 2014, 16:5093-5102 doi: 10.1039/c3ce42272k
14. [14]
  Raja D S, Luo J H, Wu C Y, et al. Cryst. Growth Des., 2013, 13:3785-3793 doi: 10.1021/cg400801s
15. [15]
  Eddaoudi M, Kim J, Rosi N, et al. Science, 2002, 295:469-472 doi: 10.1126/science.1067208
16. [16]
  Rowsell J L, Millward A R, Park K S, et al. J. Am. Chem. Soc., 2004, 126:5666-5667 doi: 10.1021/ja049408c
17. [17]
  Rowsell J L, Yaghi O M. J. Am. Chem. Soc., 2006, 128:1304-1315 doi: 10.1021/ja056639q
18. [18]
  Wang X L, Luan J, Lin H Y, et al. Polyhedron, 2014, 71:111-118 doi: 10.1016/j.poly.2013.12.044
19. [19]
  Wang X L, Mu B, Lin H Y, et al. Sci. Chi. Chem., 2013, 56:557-566 doi: 10.1007/s11426-012-4784-6
20. [20]
  Zhu A X, Lin J B, Zhang J P, et al. Inorg. Chem., 2009, 48:3882-3889 doi: 10.1021/ic802446m
21. [21]
  Sun Y X, Sun W Y. CrystEngComm, 2015, 17:4045-4063 doi: 10.1039/C5CE00372E
22. [22]
  Liu F J, Sun D, Hao H J, et al. CrystEngComm, 2012, 14:379-382 doi: 10.1039/C1CE06356A
23. [23]
  Lü C N, Chen M M, Zhang W H, et al. CrystEngComm, 2015, 17:1935-1943 doi: 10.1039/C4CE02074J
24. [24]
  SADABS, Bruker AXS Inc., Madison, Wisconsin, USA, 1997.
25. [25]
  Sheldrick G M. SHELX-97, Program for the Solution and the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
26. [26]
  Cui Y J, Yue Y F, Qian G D, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
27. [27]
  He K H, Song W C, Li Y W, et al. Cryst. Growth Des., 2012, 12:1064-1068 doi: 10.1021/cg2014495
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