Citation: XIA Li-Bin, XIAO Qing-Hui, LI Zi-Cheng, WU Dun-Cai, YOU Wei-Xiong. Structure Analysis and Optical Properties of Europium Doped Calcium Bismuth Borate Glasses for WLED[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 753-760. doi: 10.11862/CJIC.2017.103 shu

Structure Analysis and Optical Properties of Europium Doped Calcium Bismuth Borate Glasses for WLED

1.
School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China
2.
School of Metallurgy and Chemistry Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Corresponding author: YOU Wei-Xiong, you_wx@126.com
Received Date: 22 December 2016
Revised Date: 17 March 2017

Figures(6)

The Eu³⁺ doped calcium bismuth borate glasses were prepared by a rapid melt quenching technique. The general physical properties including density, molar volume, refractive index and so on were studied. Furthermore, the structure, optical properties and thermal stability of glasses with different n_B/n_Bi and CaO concentration were also investigated. The experimental results demonstrate that Eu³⁺ is melted homogeneously in glass samples and acts as a well activator. An intense emission peak at 613 nm appears in the emission spectra under 465 nm excitation. The excited and emitted spectra intensities have no obvious variation as n_B/n_Bi gradually decreasing, but that decrease with CaO concentration increasing. All glass samples present amorphous states and relative low symmetric structure. The tightness and symmetries of glass structure decrease totally as n_B/n_Bi decreasing and increase as CaO concentration increasing. The[BO₃], [BO₄], [BiO₃] and[BiO₆] units are identified in glass samples, however, six member rings consisting of[BO₃] are not observed. The glass samples possess red light under matching blue light chip, and exhibit many virtues such as well thermal stability, low melting temperature and appropriate refractive index.
- luminescence material,
- red emission,
- bismuth borate glass,
- calcium ion
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1.
沈阳化工大学材料科学与工程学院沈阳 110142