Citation: GU Yan, LIU Guan-Ting, ZOU Cheng-Heng, ZHANG Zhen, LIU Juan, SUN Ming, CHENG Gao, YU Lin. Ultrasonic Synthesis and Application in Catalytic 4-Nitrophenols Reduction of Au/Fe₃O₄[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 787-795. doi: 10.11862/CJIC.2017.102 shu

Ultrasonic Synthesis and Application in Catalytic 4-Nitrophenols Reduction of Au/Fe₃O₄

Guangdong University of Technology, School of Chemical Engineering and Light Industry, Guangzhou 510006, China

Corresponding author: YU Lin, gych@gdut.edu.cn
Received Date: 22 December 2016
Revised Date: 22 March 2017

Figures(10)

The Au/Fe₃O₄ catalyst was successfully prepared by the simple ultrasonic method and in-situ reduction method. Au was immobilized on the surface of Fe₃O₄ using APTES as an organic bridging bond to obtain monodisperse magnetic Au/Fe₃O₄. Au⁰ could not agglomerated in the condition of NH³⁺, so that it had high catalytic activity and stability. The results of XRD, HRTEM, EDS and XPS showed that Au/Fe₃O₄ has been prepared successfully. It was used to catalyze the reduction of 4-nitrophenols to 4-aminophenols, which showed high catalytic activity with rate constant of 0.225 6 min^-1. The repeatability test showed that the catalyst had good stability. After 9 cycles of reaction, the conversion rate of the reaction was still 94%.
- Au nanoparticles,
- Fe₃O₄,
- 4-nitrophenols,
- catalytic reduction
1. [1]
  Haruta M, Yamada N, Iijima S, et al. J. Catal., 1989, 115:301-309 doi: 10.1016/0021-9517(89)90034-1
2. [2]
  Yang X F, Wang A Q, Zhang T, et al. Acc. Chem. Res., 2013, 46:1740-1748 doi: 10.1021/ar300361m
3. [3]
  XIE Lin-Yan, LI Qun-Yan, WANG Zhi-Hong, et al. Chinese J. Inorg. Chem., 2010, 26(10):1756-1760
4. [4]
  HUANG Qi-Hui, ZHANG Bao-Shan, JI Guang-Bin, et al. Chinese J. Inorg. Chem., 2012, 28(10):2077-2082
5. [5]
  LIU Bing, WANG De-Ping, YAO Ai-Hua, et al. Chinese J. Inorg. Chem., 2008, 23(1):33-38
6. [6]
  Wu W, He Q G, Nie L B, et al. Nanotechnology, 2007, 18:145609-145617 doi: 10.1088/0957-4484/18/14/145609
7. [7]
  LIU Yong-Jian, CHEN Yong-Bing, LIU Min, et al. Chinese J. Inorg. Chem., 2015, 31(6):1165-1170
8. [8]
  XIAO Wang-Chuan, WANG Ye-Min, WANG Ren-Zhang, et al. Chinese J. Inorg. Chem., 2014, 30(11):2259-2563
9. [9]
  Cui L R, Lin H M, Qu F Y, et al. Eur. J. Inorg. Chem., 2014, 36:6156-6164
10. [10]
  Rostamizadeh S, Estiri H, Azad M. J. Iranian Chem. Soc., 2016, 18:1367-1374
11. [11]
  Zhou Y, Wang B W, Zhu X Q, et al. Nanotechnology, 2016, 27:215301-215310 doi: 10.1088/0957-4484/27/21/215301
12. [12]
  Liu W J, Jiang H, Yu H Q, et al. Green Chem., 2014, 16:4198-4205 doi: 10.1039/C4GC00599F
13. [13]
  Wang Z Z, Zhai S R, An Q D, et al. Eur. J. Inorg. Chem., 2015, 10:1692-1699
14. [14]
  Wang M, Tian D, Yuan L J, et al. Appl. Surf. Sci., 2013, 283:389-395 doi: 10.1016/j.apsusc.2013.06.120
15. [15]
  Fernandez J, Bandara J, Kiwi A J, et al. Langmuir, 1999, 15:185-192 doi: 10.1021/la980382a
16. [16]
  Pany S, Parida K M, Naik B. RSC Adv., 2013, 3:4976-4984 doi: 10.1039/c3ra22775h
17. [17]
  Xiong Z G, Zhang L L, Zhao X S, et al. Chem. Commun., 2010, 46:6099-6101 doi: 10.1039/c0cc01259a
18. [18]
  Zheng J M, Deng Y L, Chen X G, et al. Nanoscale, 2013, 5:4894-4901 doi: 10.1039/c3nr01075a
19. [19]
  Gazi S, Ananthakrishnan R. Appl. Catal. B, 2011, 105:317-325 doi: 10.1016/j.apcatb.2011.04.025
20. [20]
  Deng H, Li X L, Li Y D, et al. Angew. Chem., 2005, 117:2842-2845 doi: 10.1002/(ISSN)1521-3757
21. [21]
  Liu J, Sun Z K, Zhao D Y, et al. Angew. Chem. Int. Ed., 2009, 48:5875-5879 doi: 10.1002/anie.v48:32
22. [22]
  Dong F P, Guo W P, Ha C S. J. Nanopart. Res., 2012, 14:1303-1311 doi: 10.1007/s11051-012-1303-9
23. [23]
  Black D, Gao Y, Yang H, et al. Nano Lett., 2003, 3:261-264 doi: 10.1021/nl025918y
24. [24]
  Li D X, He Q, Li J B, et al. Chem. Mater., 2007, 19:412-417 doi: 10.1021/cm062290+
25. [25]
  Saha S, Pal A, Pal T, et al. Langmuir, 2010, 26:2885-2893 doi: 10.1021/la902950x
26. [26]
  Gangula A, Podila R, Rao A M, et al. Langmuir, 2011, 27:15268-15274 doi: 10.1021/la2034559
27. [27]
  Konar S, Kalita H, Pathak A, et al. J. Catal., 2016, 336:11-22 doi: 10.1016/j.jcat.2015.12.017
28. [28]
  Perez-Lorenzo M, Liz-Marzan L M, Ballauff M, et al. Chem. Soc. Rev., 2012, 41:5577-558 doi: 10.1039/c2cs35029g
29. [29]
  Du C, He S J, Chen W, et al. ChemCatChem, 2016, 8:1-6 doi: 10.1002/cctc.v8.1
1. [1]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
2. [2]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
3. [3]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
6. [6]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
7. [7]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
8. [8]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
9. [9]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
10. [10]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
11. [11]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
12. [12]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
13. [13]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
14. [14]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
15. [15]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
16. [16]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
17. [17]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
18. [18]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
19. [19]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
20. [20]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(870)
HTML views(155)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ultrasonic Synthesis and Application in Catalytic 4-Nitrophenols Reduction of Au/Fe3O4

Metrics

通讯作者: 陈斌, bchen63@163.com

Ultrasonic Synthesis and Application in Catalytic 4-Nitrophenols Reduction of Au/Fe₃O₄