Citation: WANG Yuan-You, GONG Ai-Qing, YU Wen-Hua. Synthesis and Photocatalytic Characterization of ZnO/BiOI Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(3): 509-518. doi: 10.11862/CJIC.2017.061 shu

Synthesis and Photocatalytic Characterization of ZnO/BiOI Microspheres

Department of Chemical Engineering, Yangzhou Polytechnic Institute, Yangzhou, Jiangsu 225127, China

Corresponding author: WANG Yuan-You, wangyy@ypi.edu.cn
Received Date: 8 November 2016
Revised Date: 30 December 2016

Figures(5)

Porous ZnO/BiOI microspheres composed of ultrathin nanosheets were successfully fabricated by an ethylene glycol-assisted solvothermal method, The morphology and size of the as-prepared samples were characterized by X-ray powder diffraction (XRD), field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), UV-Vis diffuse reflectance spectra (DRS), X-ray photoelectron spectroscopy (XPS) and N₂ adsorpion-desorption measurements. The photocatalytic degradation of RhB aqueous solution shows that the porous ZnO/BiOI microspheres have the highest photodegradation performance with visible light and acetaldehyde (CH₃CHO) gas degradation.This finding indicates that the heterojunction effect created between two different semiconductors is of importance in determining the dynamic properties of photogenerated charge transfer and the related photocatalytic properties.
- Porous ZnO/BiOI microspheres,
- photocatalytic,
- acetaldehyde
1. [1]
  Mukhopadhyay S, Das P P, Maity S, et al. Appl. Catal. B, 2015, 165:128-138 doi: 10.1016/j.apcatb.2014.09.045
2. [2]
  Umar A, Akhtar M S, Al-Hajry A, et al. Chem. Eng. J., 2015, 262:588-596 doi: 10.1016/j.cej.2014.09.111
3. [3]
  Chen Y, Zhao H, Liu B, et al. Appl. Catal. B, 2015, 163:189-197 doi: 10.1016/j.apcatb.2014.07.044
4. [4]
  Tian C, Zhang Q, Wu A, et al. Chem. Commun., 2012, 48: 2858-2860 doi: 10.1039/c2cc16434e
5. [5]
  Zhang H J, Chen G H, Bahnemann D W. J. Mater. Chem., 2009, 19:5089-5121 doi: 10.1039/b821991e
6. [6]
  Kayaci F, Vempati S, Ozgit-Akgun C, et al. Appl. Catal. B, 2014, 156-157:173-183 doi: 10.1016/j.apcatb.2014.03.004
7. [7]
  Wahab R, Tripathy S K, Shin H S, et al. Chem. Eng. J., 2013, 226:154-160 doi: 10.1016/j.cej.2013.02.128
8. [8]
  Pan L K, Liu X J, Sun Z, et al. J. Mater. Chem. A, 2013, 1: 8299-8326 doi: 10.1039/c3ta10981j
9. [9]
  Wu C L. Appl. Surf. Sci., 2014, 319:237-243 doi: 10.1016/j.apsusc.2014.04.217
10. [10]
  Lai Y L, Meng M, Yu Y F, et al. Appl. Catal. B, 2011, 105: 335-345 doi: 10.1016/j.apcatb.2011.04.028
11. [11]
  Kochuveedu S T, Jang Y H, Kim D H. Chem. Soc. Rev., 2013, 42:8467-8493 doi: 10.1039/c3cs60043b
12. [12]
  Sun S, Wang W, Zeng S, et al. J. Hazard. Mater., 2010, 178: 427-433 doi: 10.1016/j.jhazmat.2010.01.098
13. [13]
  Zhang X L, Zhao J L, Wang S G, et al. Int. J. Hydrogen Energy, 2014, 39:8238-8245 doi: 10.1016/j.ijhydene.2014.03.153
14. [14]
  Ai Z, Huang Y, Lee S, Zhang L. J. Alloys Compd., 2011, 509:2044-2049 doi: 10.1016/j.jallcom.2010.10.132
15. [15]
  Kibanova D, Sleiman M, Cervini-Silva J, et al. J. Hazard. Mater., 2012, 211-212:233-239 doi: 10.1016/j.jhazmat.2011.12.008
16. [16]
  Liao Y C, Xie C S, Liu Y, et al. Ceram Int., 2012, 38:4437-4444 doi: 10.1016/j.ceramint.2012.03.016
17. [17]
  Tian H, He J H, Liu L L, et al. Microporous Mesoporous Mater., 2012, 151:397-402 doi: 10.1016/j.micromeso.2011.10.003
18. [18]
  Yang L P, Liu Z Y, Shi J W, et al. Sep. Purif. Technol., 2007, 54:204-211 doi: 10.1016/j.seppur.2006.09.003
19. [19]
  You Y, Zhang S Y, Wan L, Xu D F. Appl. Surf. Sci., 2012, 258:3469-3474 doi: 10.1016/j.apsusc.2011.11.099
20. [20]
  Zhang L, Fu H, Zhang C, et al. J. Solid State Chem., 2006, 179:804-811 doi: 10.1016/j.jssc.2005.12.003
21. [21]
  Zhou J, Mullins D R. Surf. Sci., 2006, 600:1540-1546 doi: 10.1016/j.susc.2006.02.009
22. [22]
  ZhuY, Yu F, Man Y, et al. J. Solid State Chem., 2005, 178: 224-229 doi: 10.1016/j.jssc.2004.11.015
23. [23]
  Wang Y Y, Zhou G Q, Guo J, et al. Ceram Int., 2016, 42: 12467-12474 doi: 10.1016/j.ceramint.2016.04.186
24. [24]
  Zhang X, Zhang L Z, Xie T F, et al. J. Phys. Chem. C, 2009, 113:7371-7378 doi: 10.1021/jp900812d
25. [25]
  Chang Y G, Xu J, Zhang Y Y, et al. J. Phys. Chem. C, 2009, 113:18761-18767 doi: 10.1021/jp9050808
26. [26]
  Gurunathan K. Int. J. Hydrogen Energy, 2004, 29:933-940 doi: 10.1016/j.ijhydene.2003.04.001
27. [27]
  Zhang K L, Liu C M, Huang F Q, et al. Appl. Catal. B, 2006, 68:125-129 doi: 10.1016/j.apcatb.2006.08.002
28. [28]
  Jiang J, Zhang X, Sun P B, et al. J. Phys. Chem. C, 2011, 115:20555-20564 doi: 10.1021/jp205925z
29. [29]
  Coppa B J, Davis R F, Nemanich R J. Appl. Phys. Lett., 2003, 82:400-402 doi: 10.1063/1.1536264
30. [30]
  Moniz S J, Tang J. ChemCatChem, 2015, 7:1659-1667 doi: 10.1002/cctc.v7.11
31. [31]
  Chun W J, Ishikawa A, Fujisawa H, et al. J. Phys. Chem. B, 2003, 107:1798-1803 doi: 10.1021/jp027593f
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