Citation: TIAN Yue, LI Fei, ZHANG Guo-Cui, ZHOU Hong-Ping, WU Jie-Ying, TIAN Yu-Peng. Two Solid Fluorescent Organic-Inorganic Hybrids: Synthesis, Crystal Structures and Strong Red Fluorescence Emissions[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(4): 664-672. doi: 10.11862/CJIC.2017.060 shu

Two Solid Fluorescent Organic-Inorganic Hybrids: Synthesis, Crystal Structures and Strong Red Fluorescence Emissions

TIAN Yue ¹ ,
LI Fei ^1,*,, ,
ZHANG Guo-Cui ¹ ,
ZHOU Hong-Ping ¹ ,
WU Jie-Ying ¹ ,
TIAN Yu-Peng ^1,2

1.
Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: LI Fei, lfe@ahu.edu.cn
Received Date: 1 September 2016
Revised Date: 26 December 2016

Figures(7)

Two organic-inorganic hybrids, (DPASP)₂[Zn (NCS)₄]·2CH₃OH (1) and {(DPASP)₂[Cd (SCN)(NCS)₃]·2CH₃OH}_n (2), have been facilely prepared from (E)-4-(4-(diphenylamino) styryl)-1-methylpyridinium iodide (DPASPI, DPASP=(E)-4-(4-(diphenylamino) styryl)-1-methylpyridinium) at gram scale. Their crystal structures have been confirmed by single-crystal X-ray diffraction analysis, which show that the hybrids 1 and 2 consist of organic pyridium cations and metal thiocyanato anions bearing different spacial structure through self-assembly processes. Furthermore, the interactions between the ions have been investigated by ¹H NMR spectra. Finally, red photolumencent properties with enhanced quantum yields of hybrids 1 and 2 were investigated.
- organic-inorganic hybrid,
- scalable efficient synthesis,
- crystal structure,
- red photoluminescent property
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沈阳化工大学材料科学与工程学院沈阳 110142