Citation: ZHANG Yi-Qing, LIU Jia-Xiang. Hexagonal-Type ITO Nanopowders:Coprecipitation Synthesis and Photoelectric Property[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 249-254. doi: 10.11862/CJIC.2017.041 shu

Hexagonal-Type ITO Nanopowders:Coprecipitation Synthesis and Photoelectric Property

ZHANG Yi-Qing ,
LIU Jia-Xiang ^,

Beijing Key Laboratory of Electrochemical Process and Technology for Materials, State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: LIU Jia-Xiang, ljxpost@263.net
Received Date: 11 July 2016
Revised Date: 26 November 2016

Figures(6)

Hexagonal-type ITO powders were prepared by coprecipitation method, In and SnCl₄·5H₂O as raw materials, urea as precipitant and added (NH₄)₂SO₄ for dispersing. The powders' crystal shape, particle morphology, electronic and optical properties were characterized by XRD, TEM, four point probe resistance meter, optical spectral luminous apparatus and XPS. The experimental results show that with the increase amount of (NH₄)₂SO₄, powders' morphology and phase structure are changed, the morphology changes from octahedral with spherical ball to spherical ball; Without adding (NH₄)₂SO₄, ITO crystal type is cubic phase. When the molar ratios of (NH₄)₂SO₄ to In are 1:3.45 and 1:1.73, the ITO crystal type turns into hexagonal phase.Continue to add (NH₄)₂SO₄, the crystal type transforms into cubic phase structure. Cubic phase ITO shows a better electrical performance with low resistivity of 0.64 Ω·cm. Under the same excitation wavelength, hexagonal phase ITO emission light intensity is higher.
- h-ITO,
- (NH₄)₂SO₄,
- coprecipitation method,
- nanopowders,
- photoelectric property
1. [1]
  Ayeshamariam A, Kashif M, Bououdina M, et al. Ceram. Int., 2014, 40(1):1321-1328 doi: 10.1016/j.ceramint.2013.07.012
2. [2]
  Ahn M H, Cho E S, Kwon S J. Vacuum, 2014, 101:221-227 doi: 10.1016/j.vacuum.2013.08.018
3. [3]
  Solieman A, Zayed M K, Alamri S N, et al. Mater. Chem. Phys., 2012, 134(1):127-132 doi: 10.1016/j.matchemphys.2012.02.040
4. [4]
  Song P, Han D, Zhang H H, et al. Sens. Actuators B, 2014, 196:434-439 doi: 10.1016/j.snb.2014.01.114
5. [5]
  Chen L Y, Wang Z X, Zhang Z D. New J. Chem., 2009, 33(5):1109-1115 doi: 10.1039/b817588h
6. [6]
  Solieman A, Zayed M K, Alamri S N, et al. Mater. Chem. Phys., 2012, 134(1):127-132 doi: 10.1016/j.matchemphys.2012.02.040
7. [7]
  Feng X, Yang W W, Tang Q L, et al. Powder Technol., 2012, 221:164-167 doi: 10.1016/j.powtec.2011.12.059
8. [8]
  Gao L P, Ren F M, Cheng Z X, et al. CrystEngComm, 2015, 17:3268-3276 doi: 10.1039/C5CE00279F
9. [9]
  Tao B L, Zhang Y, Han D Z, et al. J. Mater. Chem. A, 2014, 2:5455-5461 doi: 10.1039/C4TA00139G
10. [10]
  Liu G D, Chen D R, Jiao X L. CrystEngComm, 2009, 11:1828-1830 doi: 10.1039/b904595n
11. [11]
  Kim B C, Kim S M, Lee J H, et al. J. Am. Ceram. Soc., 2002, 85(8):2083-2088 doi: 10.1111/jace.2002.85.issue-8
12. [12]
  LIU Lang-Ming, GONG Mingming, WEI Wen-Wu. Nonferrous Metallurgy, 1999, 28(6):32-36
13. [13]
  Gurlo A, Barsan N, Weimar U. J. Am. Chem. Soc., 2004, 126(13):4078-4079 doi: 10.1021/ja0318075
14. [14]
  ZHONG Wei-Zhuo, WANG Bu-Guo, SHI Er-Wei, et al. J. Inorg. Mater., 1997, 12(1):11-16
15. [15]
  Guptake R K, Ghosh K, Patel R, et al. J. Cryst. Growth, 2008, 310(19):4336-4339 doi: 10.1016/j.jcrysgro.2008.07.043
16. [16]
  Zhang D H, Ma H L. Appl Phys. A, 1996, 62(5):487-492 doi: 10.1007/BF01567122
17. [17]
  Yang H X, Liu L, Liang H. CrystEngComm, 2011, 13:5011-5016 doi: 10.1039/c1ce05274h
18. [18]
  Wu X C, Hong J M, Han Z J, et al. Chem. Phys. Lett., 2003, 373(1/2):28-32
19. [19]
  Chang H C, Seung Y H, Yu W S, et al. J. Mater. Chem. C, 2015, 3:854-860 doi: 10.1039/C4TC01568A
1. [1]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
2. [2]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
3. [3]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
4. [4]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
5. [5]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
6. [6]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
7. [7]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
8. [8]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
9. [9]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
10. [10]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
11. [11]
  Shuangxi Li , Huijun Yu , Tianwei Lan , Liyi Shi , Danhong Cheng , Lupeng Han , Dengsong Zhang . NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites. Chinese Chemical Letters, 2024, 35(5): 108240-. doi: 10.1016/j.cclet.2023.108240
12. [12]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
13. [13]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
14. [14]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
15. [15]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
16. [16]
  Cuiwu MO , Gangmin ZHANG , Chao WU , Zhipeng HUANG , Chi ZHANG . A(NH₂SO₃) (A=Li, Na): Two ultraviolet transparent sulfamates exhibiting second harmonic generation response. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1387-1396. doi: 10.11862/CJIC.20240045
17. [17]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
18. [18]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
19. [19]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
20. [20]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(731)
HTML views(115)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142