Citation: WANG Gui-Yan, XIA Li, YU Jun. Organosilane-Functionalized Carbon Nanospheres:Synthesis and Visible Light Photocatalytic Activity[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(2): 299-306. doi: 10.11862/CJIC.2017.022 shu

Organosilane-Functionalized Carbon Nanospheres:Synthesis and Visible Light Photocatalytic Activity

WANG Gui-Yan ^1,, ,
XIA Li ¹ ,
YU Jun ²

1.
School of Pharmaceutical Engineering, ShenYang Pharmaceutical University, Shenyang 110016, China
2.
Shenyang Center for Disease Control and Prevention, Shenyang 110031, China

Corresponding author: WANG Gui-Yan, wangguiyan2004@126.com
Received Date: 7 July 2016
Revised Date: 14 November 2016

Figures(13)

Organosilane-functionalized carbon nanospheres (SiCNs)with excellent up-and down-converted photoluminescence properties were prepared by the one-pot solvothermal method in ethylene glycol from citric acid and (3-aminopropyl)triethoxysilane (APTES). The as-prepared SiCNs were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), UV-Vis diffuse reflection spectroscopy (DRS)and photoluminescence spectra (PL). The results indicate that uniform spherical SiCNs with diameter of about 30~50 nm were synthesized at 180℃ for 5 h when the mass proportion of APTES and citric acid is 2.0. The visible-driven photocatalytic activity of SiCNs toward the degradation of methylene blue (MB)was investigated. The photocatalytic mechanism was discussed based on the active species during photocatlytic process. The results show that after 120 min visible light irradiation, the degradation rate of MB reached 99% by using SiCNs. The decomposition rate of MB was still above 96% even after 5 recycling uses, thus SiCNs show high visible light photocatalytic activity and excellent stability.
- carbon nanospheres,
- luminescence,
- photocatalyst,
- photodegradation
1. [1]
  Seifvand N, Kowsari E. RSC Adv., 2015, 5:93706-93716 doi: 10.1039/C5RA13620B
2. [2]
  Lin C, Song Y, Cao L X, et al. Nanoscale, 2013, 5:4986-4992 doi: 10.1039/c3nr01033c
3. [3]
  Wang J, Gao M M, Wei H G. J. Mater. Chem. A, 2014, 2:5703-5709 doi: 10.1039/c3ta15114j
4. [4]
  Li F, Tian F, Liu C J, et al. RSC Adv., 2015, 5:8389-8396 doi: 10.1039/C4RA14865G
5. [5]
  LI Feng, WANG Gui-Yan, LI Yong-Bo, et al. Chinese J. Inorg. Chem., 2014, 30(8):1783-1789
6. [6]
  Bhowmik T, Kundu M K, Barman S. RSC Adv., 2015, 5:38760-38773 doi: 10.1039/C5RA04913J
7. [7]
  Di J, Xia J X, Ji M X, et al. Nanoscale, 2015, 7:11433-11443 doi: 10.1039/C5NR01350J
8. [8]
  Lim S Y, Shen W, Gao Z Q. Chem. Soc. Rev., 2015, 44:362-381 doi: 10.1039/C4CS00269E
9. [9]
  Ding H, Yu S B, Wei J S, et al. ACS Nano, 2016, 10(1):484-491 doi: 10.1021/acsnano.5b05406
10. [10]
  Fernando K A S, Sahu S, Liu Y M, et al. ACS Appl. Mater. Interfaces, 2015, 7:8363-8376 doi: 10.1021/acsami.5b00448
11. [11]
  Wang H, Zhuang J Q, Velado D, et al. ACS Appl. Mater. Interfaces, 2015, 7(50):27703-27712 doi: 10.1021/acsami.5b08443
12. [12]
  Li H, Guo S J, Li C X, et al. ACS Appl. Mater. Interfaces, 2015, 7:10004-10012 doi: 10.1021/acsami.5b02386
13. [13]
  Liu R H, Huang H, Li H T, et al. ACS Catal., 2014, 4:328-336 doi: 10.1021/cs400913h
14. [14]
  Li H T, Kang Z H, Liu Y, et al. J. Mater. Chem., 2012, 22:24230-24253 doi: 10.1039/c2jm34690g
15. [15]
  Chen J, Liu W, Mao L H, Yin Y J, et al. J. Mater. Sci., 2014, 49:7391-7398 doi: 10.1007/s10853-014-8413-y
16. [16]
  Wen T, Yang B C, Guo Y Z, et al. Phys. Chem. Chem. Phys., 2014, 16:23188-23195 doi: 10.1039/C4CP03339F
17. [17]
  Chen P C, Chen Y N, Hsu P C, et al. Chem. Commun., 2013, 49:1639-1641 doi: 10.1039/c3cc38486a
18. [18]
  Wang F, Xie Z, Zhang H, et al. Adv. Funct. Mater., 2011, 21:1027-1031 doi: 10.1002/adfm.201002279
19. [19]
  Yang Y H, Cui J H, Zheng M T, et al. Chem. Commun., 2012, 48:380-382 doi: 10.1039/C1CC15678K
20. [20]
  Wang W T, Kim T, Yan Z F, et al. J. Colloid Interface Sci., 2015, 437:28-34 doi: 10.1016/j.jcis.2014.09.013
21. [21]
  Yang Z, Xu M H, Liu Y, et al. Nanoscale, 2014, 6:1890-1895 doi: 10.1039/C3NR05380F
22. [22]
  Sun J, Yang S W, Wang Z Y. Part. Part. Syst. Char., 2015, 32:434-440 doi: 10.1002/ppsc.v32.4
23. [23]
  Sahu S, Behera B, Maiti T K, et al. Chem. Commun., 2012, 48:8835-883 doi: 10.1039/c2cc33796g
24. [24]
  Kumar S, Baruah A, Tonda S, et al. Nanoscale, 2014, 6:4830-4842 doi: 10.1039/c3nr05271k
25. [25]
  Wang X, Cao L, Lu F S, et al. Chem. Commun., 2009, 25:3774-3776
26. [26]
  Su B Q, Ma Y J, Du Y L, et al. J. Electrochem. Soc., 2008, 155(10):F213-F217 doi: 10.1149/1.2961056
27. [27]
  Rafiee-Pour H A, Behpour M, Keshavarz M. Biosens. Bioelectron., 2016, 77:202-207 doi: 10.1016/j.bios.2015.09.025
28. [28]
  Farsi H, Hosseini S A. J. Solid State Electrochem., 2013, 17:2079-2086 doi: 10.1007/s10008-013-2068-5
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沈阳化工大学材料科学与工程学院沈阳 110142