Citation: ZHAO Di, ZHANG Bo, DUAN Zhao-Juan, LI Ai-Chang. Ag₂S/Ag₃PO₄/Ni Thin Films: Preparation and Photocatalytic Activity for Rhodamine B[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2158-2164. doi: 10.11862/CJIC.2016.276 shu

Ag₂S/Ag₃PO₄/Ni Thin Films: Preparation and Photocatalytic Activity for Rhodamine B

1.
Faculty of Chemistry and Material Science, Langfang Teachers College, Langfang, Hebei 065000, China

Corresponding author: LI Ai-Chang,
Received Date: 28 July 2016
Available Online: 8 October 2016
Fund Project:

Ag₂S/Ag₃PO₄/Ni composite thin films were prepared by electrochemical method. The surface morphology, phase structure, optical characteristics and band structure of the thin film were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS), respectively. Its photocatalytic properties and stability were evaluated with rhodamine B (RhB) as a model compound. Using a method of adding active species scavenger to the solution, mechanism of photocatalytic degradation of the film was explored. The results show that the Ag₂S/Ag₃PO₄/Ni thin film is composed of uniform spherical nanoparticles. The photocatalytic activity of the as-prepared Ag₂S/Ag₃PO₄/Ni thin film was higher than those of pure Ag₃PO₄/Ni thin film and Ag₂S/Ni thin film respectively. The film maintains nearly 100% of their corresponding initial photocatalytic activity after 6 cycles. Furthermore, the photodegradation mechanism of the composite films for RhB under the visible light was preliminary proposed.
- Ag₂S/Ag₃PO₄/Ni thin film;electrochemical preparation;photocatalysis;rhodamine B;reaction mechanism
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沈阳化工大学材料科学与工程学院沈阳 110142

Ag2S/Ag3PO4/Ni Thin Films: Preparation and Photocatalytic Activity for Rhodamine B

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通讯作者: 陈斌, bchen63@163.com

Ag₂S/Ag₃PO₄/Ni Thin Films: Preparation and Photocatalytic Activity for Rhodamine B