Citation: ZHANG Chang-Li, TIAN Jia-Jin, SHAO Yang, XU Jian. Benzothiazole-Based Zn2+-Specific Fluorescent Probe and Its Cell Imaging Application[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2069-2074. doi: 10.11862/CJIC.2016.274
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A fluorescent probe 2-((2-(benzo[d]thiazol-2-yl)hydrazono)methyl)-5-(diethylamino)phenol (BHP) was designed and synthesized as a Zn2+ selective fluorescent chemosensor. It demonstrates Zn2+-specific emission enhancement, while many other ions such as Cd2+, Fe2+, Ni2+, Pb2+, Hg2+, Al3+, Mn2+, Ag+, Cu2+, Co2+, Na+, K+, Mg2+ and Ca2+, have no response. Notably, this chemosensor can distinguish Zn2+ from Cd2+. Its binding stoichiometry with Zn2+ is 1:1 ratio. Its pH-independent Zn2+-induced emission enhancement in physiological condition and cell permeability make it an effective intracellular Zn2+ imaging agent.
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