Citation: LIU Xiang, HAN Jing, YU Zhong, WANG Xiao-Xiang. Three Coordination Polymer Microcrystals:Size-Controlled Syntheses and Photocatalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1931-1941. doi: 10.11862/CJIC.2016.253
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Microcrystals of Ni(Ⅱ), Co(Ⅱ) and Zn(Ⅱ) coordination polymers based on 4,4'-oxybisbenzoic acid (oba) and 4,4'-bipyridine (4,4'-bpy) with sizes ranging from 10 to 250 μm were prepared hydrothermally by regulating the amount of NEt3, reaction time and reaction temperature. The crystal sizes, morphologies and structures were characterized and analyzed by scanning electron microscopy (SEM) and X-ray powder diffraction (XRPD). Photocatalytic measurements demonstrate that three polymers have excellent degradation capacities of organic dyes such as rhodamine B (RhB), methyl orange (MO) and methylene blue (MB) and the degradation rate increases with the decrease of catalyst sizes. Remarkably, the photocatalytic performance of Ni(Ⅱ) complex (30 μm) for RhB exceeds that of the nano-sized TiO2 under same experimental conditions. In addition, XRPD studies show three coordination polymers are structurally stable after one cycle of photodegradation and thus can be utilized repeatedly as photocatalysts.
-
-
[1]
[1] Thompson T L, Yates J T. Chem. Rev., 2006,106(10):4428-4453
-
[2]
[2] Mills A, Hunte S L. Chem. Rev., 1997,108:1-35
-
[3]
[3] Ayoub K, van Hullebusch E D, Cassir M, et al. J. Hazard. Mater., 2010,178(1/2/3):10-28
-
[4]
[4] Akpan U G, Hameed B H. J. Hazard. Mater., 2009,170(2/3): 520-529
-
[5]
[5] Du J J, Yuan Y P, Sun J X, et al. J. Hazard. Mater., 2011, 190(1/2/3):945-951
-
[6]
[6] Murray L J, Dinca M, Long J R. Chem. Soc. Rev., 2009,38(5):1294-1314
-
[7]
[7] Ferey G. Nat. Mater., 2003,2(3):136-137
-
[8]
[8] Zeng M H, Wang Q X, Tan Y X, et al. J. Am. Chem. Soc., 2010,132(8):2561-2563
-
[9]
[9] Liu W T, Ou Y C, Xie Y L, et al. Eur. J. Inorg. Chem., 2009,28:4213-4218
-
[10]
[10] ZHAO Nan(赵楠), DENG Hong-Ping(邓洪萍), SHU Mou-Hai(舒谋海), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(7):1213-1217
-
[11]
[11] Silva C G, Corma A, Garcia H. J. Mater. Chem., 2010,20(16):3141-3156
-
[12]
[12] Lin H, Maggard P A. Inorg. Chem., 2008,47(18):8044-8052
-
[13]
[13] Liao Z L, Li G D, Bi M H, et al. Inorg. Chem., 2008,47(11): 4844-4853
-
[14]
[14] Yu Z T, Liao Z L, Jiang Y S, et al. Chem. Commun., 2004, (16):1814-1815
-
[15]
[15] Yu Z T, Liao Z L, Jiang Y S, et al. Chem. Eur. J., 2005,11(9):2642-2650
-
[16]
[16] Peng X, Manna L, Yang W, et al. Nature, 2000,404(6773): 59-61
-
[17]
[17] Horn D, Rieger J. Angew. Chem, Int. Ed., 2001,40(23): 4330-4361
-
[18]
[18] Chen J, Herricks T, Xia Y. Angew. Chem, Int. Ed., 2005,44(17):2589-2592
-
[19]
[19] Taylor K M L, Jin A, Lin W. Angew. Chem. Int. Ed., 2008, 120(40):7836-7839
-
[20]
[20] Guo L, Liu C, Wang R, et al. J. Am. Chem. Soc., 2004,126(14):4530-4531
-
[21]
[21] Tsuruoka T, Furukawa S, Takashima Y, et al. Angew. Chem. Int. Ed., 2009,48(26):4739-4743
-
[22]
[22] FAN Ying-Hua(范英华), LUO Qin(雒琴), LIU Gui-Xia (刘桂霞), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(3):627-632
-
[23]
[23] Guo H, Zhu Y, Wang S, et al. Chem. Mater., 2012,24(3): 444-450
-
[24]
[24] Sun H L, Shi H, Zhao F, et al. Chem. Commun., 2005,(34): 4339-4341
-
[25]
[25] WANG Jun(王俊), CAO Wei-Man(曹伟曼), YANG Hong (杨红), et al. J. Shanghai Normal Univ.(上海师范大学学报), 2010,39(2):166-174
-
[26]
[26] Han J, Yu Z, He X, Li P, et al. Inorg. Chim. Acta, 2012, 388(1):98-101
-
[27]
[27] Ji W J, Hu M C, Li S N, et al. CrystEngComm, 2014,16(17): 3474-3477
-
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