Citation: LIU Ying, HU Jun, YAN Jie, ZHI Xia, ZHANG Cai-Ling, PAN Qin-He. Template-Directed Synthesis of a Series of Rare-Earth Metal Oxalate Compounds Using Co(Ⅲ) Complex as Template[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1559-1564. doi: 10.11862/CJIC.2016.197 shu

Template-Directed Synthesis of a Series of Rare-Earth Metal Oxalate Compounds Using Co(Ⅲ) Complex as Template

LIU Ying ¹ ,
HU Jun ¹ ,
YAN Jie ¹ ,
ZHI Xia ¹ ,
ZHANG Cai-Ling ¹ ,
PAN Qin-He ^1,2,*,,

1.
Key Study Center of the National Ministry of Education for Tropical Resources Utilization, College of Materials and Chemical Engineering, Hainan University, Haikou 570228, China
2.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

Corresponding author: PAN Qin-He, panqinhe@163.com
Received Date: 12 April 2016
Revised Date: 25 July 2016

Figures(4)

Under hydrothermal conditions, three novel complexes {[Co(en)₃]·[KLa₂(C₂O₄)₅(H₂O)₆]·H₂O}_n (HNU-9), {[Co(dien)₂][La₂(C₂O₄)₄(H₂O)₂]·xH₂O}_n (HNU-11) and {K₃[Co(dien)₂][La₄(C₂O₄)₉(H₂O)₂]·5H₂O}_n (HNU-12) were synthesized by using Co(Ⅲ) complexes as template. Different templates ([Co(en)₃]³⁺, [Co(dien)₂]³⁺, K⁺+[Co(dien)₂]³⁺) exist in compounds in different ways, leading to different three-dimensional framework structures. Interesting, the structures of HNU-11 and HNU-12 present the novel topology structure due to different coordination modes of the central La³⁺. Therefore, it is suggested that rare earth metal with higher coordination number more easily lead to form complexes with novel structure. CCDC: 1495537, HNU-9; 1495538, HUN-11; 1495539, HUN-12.
- rare-earth-oxalate complexes,
- template,
- transition metal complexes,
- solvothermal synthesis
1. [1]
  Chen D M, Zhang X P, Shi W, et al. Cryst. Growth Des., 2014, 14(12):6261-6268 doi: 10.1021/cg500942g
2. [2]
  XIA Jun, LI Tian-Tian, GONG Xiao-Lin, et al. Chinese J. Inorg. Chem., 2014, 30 (07):1535-1541
3. [3]
  KUANG Yun-Fei, LI Chang-Hong, YANG Ying-Qun, et al. Chinese J. Inorg. Chem., 2007, 23(03):541-544
4. [4]
  Duan Y C, Chen L Y, Peng Y, et al. Chem. Commun., 2014, 50:8651-8654 doi: 10.1039/C4CC02818J
5. [5]
  Zhang Z J, Zaworotko M J. Chem. Soc. Rev., 2014, 43:5444-5455 doi: 10.1039/C4CS00075G
6. [6]
  Vaidhyanathan R, Natarajan S, Rao C N R. Solid State Sci., 2002, 4(5):633-639 doi: 10.1016/S1293-2558(02)01307-9
7. [7]
  Fang Q R, Zhu G S, Xue M, et al. Cryst. Growth Des., 2007, 8(1):319-329
8. [8]
  Liu Y, Lin X, Liu G, et al. J. Inorg. Organomet. Polym., 2012, 22(5):946-951 doi: 10.1007/s10904-012-9701-0
9. [9]
  Sha J Q, Sun J W, Wang C, et al. CrystEngComm, 2012, 14 (15):5053-5064 doi: 10.1039/c2ce00025c
10. [10]
  Wang X L, Xu C, Lin H Y, et al. Transition Met. Chem., 2012, 37(8):751-756 doi: 10.1007/s11243-012-9647-7
11. [11]
  Pan Q H, Chen Q, Song W C, et al. CrystEngComm, 2010, 12 (12):4198-4204 doi: 10.1039/c002658a
12. [12]
  Chygorin E N, Petrusenko S R, Kokozay V N, et al. Acta Crystallogr. Sect. E, 2012, 68(3):m233-m234 doi: 10.1107/S1600536812003224
13. [13]
  Du Y, Yu J, Wang Y, et al. J. Solid State Chem., 2004, 177 (9):3032-3037 doi: 10.1016/j.jssc.2004.05.017
14. [14]
  Pan Q, Li J, Ren X, et al. Chem. Mater., 2008, 20(2):370-372 doi: 10.1021/cm702439v
15. [15]
  Han Y, Li Y, Yu J, et al. Eur. J. Inorg. Chem., 2012, 2012 (1):36-39 doi: 10.1002/ejic.201100816
16. [16]
  TIAN Rui-Jing, XU Yi-Lu, FENG Li-Juan, et al. Nat. Sci. J. Hainan University, 2014, 32(03):225-232
17. [17]
  Pan Q H, Tian R J, Liu S J, et al. Chin. Chem. Lett., 2013, 24:861 doi: 10.1016/j.cclet.2013.06.025
18. [18]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, 64:112-122 doi: 10.1107/S0108767307043930
19. [19]
  Spek A L. J. Appl. Crystallogr., 2003, 36:7-13 doi: 10.1107/S0021889802022112
20. [20]
  Dan M, Rao C N R. Angew. Chem. Int. Ed., 2006, 45:281-285 doi: 10.1002/(ISSN)1521-3773
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