Syntheses, Crystal Structures and DNA-Binding Properties of Co (Ⅲ)/Cd (Ⅱ) Complexes with Quinoline Thiosemicarbazone Ligand
- Corresponding author: YAN Ling-Ling, yll@hpu.edu.cn WANG Yuan, wangyuan08@hpu.edu.cn
Citation: MAO Pan-Dong, YAN Ling-Ling, WANG Wen-Jing, YANG Qian-Qian, CUI Meng-Qiang, WANG Yuan, WU Wei-Na. Syntheses, Crystal Structures and DNA-Binding Properties of Co (Ⅲ)/Cd (Ⅱ) Complexes with Quinoline Thiosemicarbazone Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 555-560. doi: 10.11862/CJIC.2016.064
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Hydrogen bonds shown in dashed line; H atoms for C-H bonds are ommited for clarity; Symmetry code: ⅰ 1-x, y, 0.5-z; ⅱ 1.5-x, 1.5-y, 1-z; ⅲ-0.5+x, 1.5-y, -0.5+z; ⅴ-x, y, 0.5-z; ⅵ 1-x, y, 1.5-z; ⅶ-x, 2-y, 1-z; ⅷ 1-x, 2-y, 1-z
Inset: plots of cDNA/(εA-εF) vs cDNA of the titration of DNA with the complex 1, where εA and εF corresponded to the apparent extinction coefficient and the extinction coefficient for free complex 1, respectively; ccomplex=10 μmol·L-1, cDNA=0~20 μmol·L-1
ccomplex=10 μmol·L-1, cDNA=0~10 μmol·L-1