Citation: ZHAO Qiang, LIU Xiu-Ming, FENG Rui, ZHANG Ying-Hui, KONG Man-Man, LIU Yang. Polypyridyl Ligands-Based Double-Decker Triggered by Silver (Ⅰ) Coordination: Crystal Structures and Spectroscopic Analysis[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 537-544. doi: 10.11862/CJIC.2016.060 shu

Polypyridyl Ligands-Based Double-Decker Triggered by Silver (Ⅰ) Coordination: Crystal Structures and Spectroscopic Analysis

1.
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China
2.
School of matrerials science and engineering, Nankai University, Tianjin 300071, China

Corresponding author: ZHANG Ying-Hui, zhangyhi@nankai.edu.cn
Received Date: 5 September 2015
Revised Date: 6 January 2016

Figures(5)

Three Ag (Ⅰ) coordination complexes, namely [Ag (dpq)(NO₃)₂]_n (1), [Ag₄ (tppq)₂(NO₃)₄](2) and [Ag₆(hpdq)₂(NO₃)₆](3) have been synthesized based on three polypyridyl ligands: 2, 3-di (pyridin-2-yl) quinoxaline (dpq), 2, 3, 7, 8-tetra (pyridine-2-yl) pyrazino[2, 3-g]-quinoxaline (tppq) and 2, 3, 6, 7, 10, 11-hexakis (2-pyridyl) dipyrazino[2, 3-f:2′, 3′-h]quinoxaline) (hpdq), respectively. Single crystal X-ray diffraction analyses reveal that complexes 1~3 assembled based on distinct double-decker unit comprising two respective polypyridyl ligands but four, four, and six Ag (Ⅰ) ions, respectively. Among them, The double-decker units in 1 and 2 both extended to two dimensional net via the coordination interaction between Ag (Ⅰ) and NO₃^- anion, while that in 3 to three dimensional net via C-H…O hydrogen bond. Furthermore, the coordintion interaciton of polypyridyl ligands and Ag (Ⅰ) ion in solution was also investigated by UV-Vis absorption and fluorescence spectroscopic analyses, which witnesses the much more sensitive spectral response of hpdq to the additon of Ag (Ⅰ) ion than other two ligands. CCDC: 868734, 1; 868735, 2; 790268, 3.
- polypyridyl ligands,
- metal-organic coordination complexes,
- self-assembly,
- UV-Vis spectrum,
- fluorescence spectrum
1. [1]
  Ma L, Mihalcik D J, Lin W. J. Am. Chem. Soc., 2009, 131: 4610-4612 doi: 10.1021/ja809590n
2. [2]
  Li Y P, Yang H R, Zhao Q, et al. Inorg. Chem., 2012, 51: 9642-9648 doi: 10.1021/ic300738e
3. [3]
  Yang X L, Wu C D. Inorg. Chem., 2014, 53:4797-4799 doi: 10.1021/ic500531k
4. [4]
  Zhang Y B, Furukawa H, Ko N, et al. J. Am. Chem. Soc., 2015, 137:2641-2650 doi: 10.1021/ja512311a
5. [5]
  Xue D X, Cairns A J, Belmabkhout Y, et al. J. Am. Chem. Soc., 2013, 135:7660-7667 doi: 10.1021/ja401429x
6. [6]
  Tian D, Chen Q, Li Y, et al. Angew. Chem. Int. Ed., 2014, 53:837-841 doi: 10.1002/anie.201307681
7. [7]
  Wang Y T, Fan H H, Wang H Z, et al. Inorg. Chem., 2005, 44:4148-4150 doi: 10.1021/ic0504137
8. [8]
  Harris K, Sun Q F, Sato S, et al. J. Am. Chem. Soc., 2013, 135:12497-12499 doi: 10.1021/ja4043609
9. [9]
  Zhao Q, Liu X M, Song W C, et al. Dalton Trans., 2012, 41: 6683-6688 doi: 10.1039/c2dt00002d
10. [10]
  Li X H, Chen Z, Zhao Q, et al. Inorg. Chem., 2007, 46:5518-5527 doi: 10.1021/ic062041n
11. [11]
  Osuga T, Murase T, Fujita M. Angew. Chem. Int. Ed., 2012, 51:12199-12201 doi: 10.1002/anie.v51.49
12. [12]
  Cui Y, Lee S J, Lin W. J. Am. Chem. Soc., 2003, 125:6014-6015 doi: 10.1021/ja029926s
13. [13]
  Lubick N. Environ. Sci. Technol., 2008, 42:8617-8617 doi: 10.1021/es8026314
14. [14]
  Hamasaki Y, Nakashima N, Niidome Y. J. Phys. Chem. C, 2013, 117:2521-2530 doi: 10.1021/jp306469s
15. [15]
  Njua E Y, Steiner A, Stahl L. Inorg. Chem., 2010, 49:2163-2172
16. [16]
  Zhang X H, Zhao Q, Liu X M, et al. Talanta, 2013, 108:150-156 doi: 10.1016/j.talanta.2013.02.071
17. [17]
  Nakamura T, Ube H, Shionoya M. Angew. Chem. Int. Ed., 2013, 52:12096-12100 doi: 10.1002/anie.201306510
18. [18]
  Li X, Xu H, Kong F, et al. Angew. Chem. Int. Ed., 2013, 52: 13769-13773 doi: 10.1002/anie.201307650
19. [19]
  Liu C S, Chen P Q, Yang E C, et al. Inorg. Chem., 2006, 45: 5812-5821 doi: 10.1021/ic060087a
20. [20]
  Xiao Z Y, Zhao X, Jiang X K, et al. Chem. Mater., 2011, 23: 1505-1511 doi: 10.1021/cm103182e
21. [21]
  Zhao Q, Li R F, Xing S K, et al. Inorg. Chem., 2011, 50: 10041-10046 doi: 10.1021/ic2008182
22. [22]
  Sheldrick G M. SHELXTL Ver6. 1, Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany, 1998.
23. [23]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany, 1997.
24. [24]
  Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement. University of Göttingen, Germany, 1997.
25. [25]
  Spek A L. PLATON, Utrecht University, Utrecht, The Netherlands, 2008.
26. [26]
  Tan C H, Yang S H, Champness N R, et al. Chem. Commun., 2011, 47:4487-4489 doi: 10.1039/c1cc10378d
27. [27]
  Yang W B, Greenaway A, Lin X, et al. J. Am. Chem. Soc., 2010, 132:14457-14469 doi: 10.1021/ja1042935
28. [28]
  Zhang Z Y, Deng Z P, Huo L H, et al. Inorg. Chem., 2013, 52:5914-5923 doi: 10.1021/ic400055t
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沈阳化工大学材料科学与工程学院沈阳 110142