Citation: ZHAO Hai-Tao, LIU Rui-Ping, ZHANG Qiang, WANG Qiao, MA Rui-Ting. Synthesis and Magnetocaloric Effect of Monodisperse Ni_xZn_1-xFe₂O₄ Nanoparticles[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 63-68. doi: 10.11862/CJIC.2016.015 shu

Synthesis and Magnetocaloric Effect of Monodisperse Ni_xZn_1-xFe₂O₄ Nanoparticles

School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, China

Corresponding author: ZHAO Hai-Tao, zht95711@163.com
Received Date: 8 July 2015
Revised Date: 16 October 2015

Figures(6)

Ni_1-xZn_xFe₂O₄ ferrites (x=0, 0.3, 0.5, 0.7 and 1.0) nanoparticles have been achieved by the polyol process using triethylene glycol as a solvent and acetylacetonate metal salts as precursors. The structure, morphology, magnetic properties and magnetocaloric effect under alternating magnetic field of resultant particles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and vibrating sample magnetometry (VSM). The results show that NiZn ferrites nanoparticles have uniform size and good dispersibility with approximate spherical shape. The average sizes are about 4~5 nm. The monodisperse Ni_xZn_1-xFe₂O₄ nano-particles show a typical ferrimagnetic behavior at room temperature. The saturation magnetization increases and then decreases with the increase of Ni²⁺ concentration. The maximum saturation magnetization with concentration of Ni²⁺ up to x=0.5 is determined to be 29.38 emu·g^-1. The temperature of Ni_0.5Zn_0.5Fe₂O₄ ferrites can reach up to 313 K under a 382 kHz magnetic field which reveals its sufficient heating ability.
- NiZn ferrites,
- polyol process,
- magnetic properties,
- magnetocaloric effect
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Synthesis and Magnetocaloric Effect of Monodisperse Ni_xZn_1-xFe₂O₄ Nanoparticles