Citation: XU Shan, LU Lin, LIU Lian, LUO Yi-Wen, WANG Shi-Quan, LIU Jian-Wen, LI Guo-Hua, FENG Chuan-Qi. Synthesis and Electrochemical Characteristics of Clew-like α-MnO₂ as Cathode Material for Lithium Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 124-130. doi: 10.11862/CJIC.2016.013 shu

Synthesis and Electrochemical Characteristics of Clew-like α-MnO₂ as Cathode Material for Lithium Ion Battery

XU Shan ^1,2 ,
LU Lin ^1,2 ,
LIU Lian ^1,2 ,
LUO Yi-Wen ^1,2 ,
WANG Shi-Quan ^1,2,*,, ,
LIU Jian-Wen ^1,2 ,
LI Guo-Hua ³ ,
FENG Chuan-Qi ^1,2

1.
Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062, China
2.
Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan 430062, China
3.
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310032, China

Corresponding author: WANG Shi-Quan, wsqhao@126.com
Received Date: 7 September 2015
Revised Date: 19 October 2015

Figures(6)

Clew-like α-MnO₂ was synthesized by a solution phase synthesis method using MnSO₄ and (NH₄)2S2O8 as reactants and Ag⁺ ions as catalyst. The synthetic materials were characterized by XRD, SEM and TEM. It was found that the reaction temperature and reaction time have much influence on the crystallinity and morphology of the products. The electrochemical properties of the final products were tested by galvanostatic charge/discharge profile measurement and cyclic voltammetry (CV). The results show that the product prepared at 25 ℃ for 2 days as cathode material for lithium ion battery, exhibits excellent cycling stability (124 mAh·g^-1 after 100 cycles) due to its unique morphology. The clew-structure α-MnO₂ could be a potential cathode material for the application of lithium ion batteries (LIBs).
- clew-like α-MnO₂,
- solution phase synthesis method,
- lithium ion battery
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Electrochemical Characteristics of Clew-like α-MnO2 as Cathode Material for Lithium Ion Battery

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Characteristics of Clew-like α-MnO₂ as Cathode Material for Lithium Ion Battery