Citation: LU Ning-Yue, ZHOU Fan, FAN Bin-Bin, LI Rui-Feng. Pt/MIL-101(Cr) for the Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2324-2330. doi: 10.11862/CJIC.2015.314
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MIL-101(Cr) supported Pt nanoparticles (Pt/MIL-101(Cr)) catalyst was prepared by a facile impregna-tion method and used as an efficient catalyst for selective hydrogenation of cinnamaldehyde (CAL). The results of XRD, TEM and N2 adsorption and catalytic evaluation showed that Pt loadings greatly influenced the size of the supported nanoparticles on MIL-101(Cr) and the selectivity to cinnamyl alcohol (COL). Pt/MIL-101(Cr) catalyst with a low Pt loading (1.0%) exhibited much higher catalytic activity and COL selectivity in the selective hydrogenation of CAL as compared with Pt nanoparticles supported on other MOFs or inorganic supports, and its activity and selectivity to COL can reach 96.5% and 86.2% under optimized reaction conditions, respectively. The prepared Pt/MIL-101(Cr) catalyst is stable and can be reused at least five times without significant loss in the activity and selectivity. The excellent catalytic performance of Pt/MIL-101(Cr) is greatly related with the unique structure and surface property of MIL-101(Cr) support.
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