Citation: WANG Gui-Xian, CAO Ke-Li, XIA Yan, FENG Yun-Long. Syntheses and Crystal Structures of Mn(Ⅱ) and Ca(Ⅱ) Coordination Polymers Based on 5-(4-(2,6-Di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2337-2342. doi: 10.11862/CJIC.2015.311 shu

Syntheses and Crystal Structures of Mn(Ⅱ) and Ca(Ⅱ) Coordination Polymers Based on 5-(4-(2,6-Di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic Acid

WANG Gui-Xian ^1,2 ,
CAO Ke-Li ² ,
XIA Yan ² ,
FENG Yun-Long ^2,,

1.
1 Department of chemistry and chemical engineering, Lishui University, Lishui, Zhejiang 323000, China;
2.
2 Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: FENG Yun-Long,
Received Date: 22 April 2015
Available Online: 11 October 2015
Fund Project: 国家自然科学基金(No.21173197)资助项目。 (No.21173197)

Two new metal-organic coordination polymers {[MnL]·0.5H₂O}_n (1),{[CaL(H₂O)₂]·H₂O}_n (2) (H₂L=5-(4-(2,6-di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic acid) have been synthesized under solvothermal reaction and characterized by single crystal X-ray diffraction analysis. 1 features a novel 3D supramolecular network built by different monochiral sheets with (3,3)-connected 2D net. 2 displays a 1D inorganic-chain linked by carboxylate oxygen atoms of L^2- with Ca(Ⅱ) ions. Thermogravimetric analyses (TGA) have been measured for 1 and 2. Luminescent properties of 2 were investigated.
- coordination polymer;5-(4-(2,6-di(pyrazin-2-yl)pyridin-4-yl)phenoxy)isophthalic acid;crystal structure;luminescent property
1. [1]
  [1] Zhao S N, Su S Q, Song X Z, et al. Cryst. Growth Des., 2013,13:2756-2765
2. [2]
  [2] Chen J, Feng Y L, Jiang Z G, et al. CrystEngComm, 2011, 13:6071-6076
3. [3]
  [3] Lin Z J, Lu J, Hong M C, et al. Chem. Soc. Rev., 2014,43: 5867-5895
4. [4]
  [4] You Y, Yang H, Chuang J W, et al. Angew. Chem. Int. Ed., 2010,49:3757-3761
5. [5]
  [5] Miyata K, Konno Y, Nakanishi T, et al. Angew. Chem., 2013, 125:6541-6544
6. [6]
  [6] Sumida K, Stück D, Mino L, et al. J. Am. Chem. Soc., 2013, 135:1083-1091
7. [7]
  [7] Bradshaw D, Claridge J B, Cussen E J, et al. Acc. Chem. Res., 2005,38:273-282
8. [8]
  [8] Herm Z R, Swisher J A, Smit B, et al. J. Am. Chem. Soc., 2011,133:5664-5667
9. [9]
  [9] Zheng S T, Mao C Y, Wu T, et al. J. Am. Chem. Soc., 2012, 134:11936-11939
10. [10]
  [10] Eslava S, Papageorgiou A C, Beaumont S K, et al. Chem. Mater., 2010,22:5174-5178
11. [11]
  [11] Ma Z, Moulton B. Coord. Chem. Rev., 2011,255:1623-1641
12. [12]
  [12] Sheldrick G M. SHELXS 97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
13. [13]
  [13] Sheldrick G M. SHELXTL 97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
14. [14]
  [14] Zhan C H, Jiang M X, Feng Y L, et al. CrystEngComm, 2010, 12:420-424
15. [15]
  [15] Cao K L, Zhang Y P, Cai Y N, et al. J. Solid State Chem., 2014,215:34-42
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