Citation: LI Xiao-Jing, WU Wei-Na, XU Zhou-Qing, LI Shou-Jie, ZHAO Liang. Two Cadmium(Ⅱ) Complexes of an Acylhydrazone Ligand Bearing Quinoline Unit: Syntheses, Structures and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2265-2271. doi: 10.11862/CJIC.2015.303
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Two complexes [Cd(L)(H2O)(NO3)2] (1) and [Cd(L)I2]·CH3OH (2) (L=4-hydroxy-N-((quinolin-8-yl)methylene)benzohydrazide) have been synthesized and structurally determined by single-crystal X-ray diffraction. The results show that the Cd(Ⅱ) ion in 1 with a mono-capped trigonal prismatic geometry is surrounded by one acylhydrazone ligand with N2O donor set, one water molecule, one mono-dendate and one bidendate nitrate anions. However, the coordination geometry of the Cd(Ⅱ) ion in 1 is a distorted tetragonal pyramid with oxygen and two nitrogen atoms provided by the ligand L and two iodide anions. The thermal stabilities and luminescent properties of both complexes are also investigated in detail.
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