Citation: SHI Wei-Dong, ZHENG De-Hua, WANG Mei. Preparation and Crystal Structures of Cobalt and Nickel Complexes Containing a Pyridine-Amine Polydentate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2205-2212. doi: 10.11862/CJIC.2015.297
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Four new cobalt and nickel complexes containing a polypyridine-amine ligand were designed and prepared, namely, [M(L1)](BF4)2 (L1=N,N,N',N'-tetrakis(2-pyridylmethyl)ethane-1,2-diamine; C1, M=Co; C2, M=Ni) and [M(L2)](BF4)n (L2=N,N,N',N'-tetrakis(2-pyridylmethyl)propane-1,3-diamine; C3 M=Co, n=3; C4, M=Ni, n=2). These complexes were characterized by infrared spectroscopy (IR) and element analysis (EA). The structures of the complexes were determined by X-ray single crystal diffraction. The four complexes all belong to the monoclinic crystal system but with different space groups (C1, Cc; C2, P21/n; C3, C2/c; C4, P21/c). Different three-dimensional packing structures were found for these complexes.
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