Citation: GAO Peng, BING Ying-Ying, ZHANG Ling-Ling, HU Ming. Five Transition Metal Complexes with 5-Hydroxy-pyridine-2-carboxylic Acid: Syntheses, Crystal Structures and Luminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2236-2242. doi: 10.11862/CJIC.2015.287
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Five transition metal complexes based on the 5-hydroxy-pyridine-2-carboxylic acid (H2L) were synthesized under hydrothermal conditions, namely, [M(HL)2(H2O)2] (M=Zn, 1; Mn, 2; Co, 3; Ni, 4), [Cu(HL)2] (5). Compounds 1~5 were structurally characterized by the elemental analyses, infrared spectra, and single crystal X-ray diffractions. The structural analyses show that 1~5 are discrete mononuclear complexes, which are extended to form the 3D supramolecular frameworks by hydrogen bonds interactions. The solid-state photoluminescence of 1 and thermal properties of 1~5 were further explored, respectively.
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-
[1]
[1] Falkowski J M, Wang C, Liu S, et al. Angew. Chem. Int. Ed., 2011,50:8674-8678
-
[2]
[2] Wang C, Xie Z, deKrafft K E, et al. J. Am. Chem. Soc., 2011,133:13445-13454
-
[3]
[3] Halder G J, Kepert C J, Moubaraki B, et al. Science, 2002, 298:1762-1765
-
[4]
[4] Zhang X M, Wang Y Q, Wang K, et al. Chem. Commun., 2011,47:1815-1817
-
[5]
[5] Chen X M, Aubin S J M, Wu Y L, et al. J. Am. Chem. Soc., 1995,117:9600-9601
-
[6]
[6] Ma L Q, Mihalcik D J, Lin W B. J. Am. Chem. Soc., 2009, 131:4610-4612
-
[7]
[7] Harbuzaru B V, Corma A, Rey F, et al. Angew. Chem. Int. Ed., 2009,48:6476-6479
-
[8]
[8] Wang J, Lin Z J, Ou Y C, et al. Inorg. Chem., 2008,47:190- 199
-
[9]
[9] Cui Y, Yue Y, Qian G, et al. Chem. Rev., 2012,112:1126- 1162
-
[10]
[10] Aleenfort M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009,38:1330-1352
-
[11]
[11] (a)Aijaz A, Lama P, Bharadwaj P K. Inorg. Chem., 2010,49: 5883-588
-
[12]
(b)Bai Z S, Qi Z P, Lu Y, et al. Cryst. Growth Des., 2008,8: 1924-1931
-
[13]
(c)Zhou Z, He X, Zhao Y M, et al. Dalton Trans., 2009,15: 2802
-
[14]
(d)Lan Y Q, Li S L, Shao K Z, et al. Cryst. Growth Des., 2009,9:737-742
-
[15]
(e)Ye J, Zhang P, Ye K, et al. Inorg. Chem. Commun., 2006, 9:744-747
-
[16]
[12] Xu X X, Liu X X, Sun T, et al. J. Coord. Chem., 2009,62: 2755
-
[17]
[13] Kim J, Chen B, Reineke T M, et al. J. Am. Chem. Soc., 2001,123:8239-8247
-
[18]
[14] Dybtsev D N, Chun H, Kim K. Angew. Chem. Int. Ed., 2004,43:5033-5036
-
[19]
[15] Aghabozorg H, Firoozi N, Roshan L, et al. J. Iran. Chem. Soc., 2011,8:992-1005
-
[20]
[16] (a)Tian A X, Han Z G, Peng J, et al. Inorg. Chim. Acta, 2008,361:1332-1338
-
[21]
(b)Aksoy M S, Yilmaz V T, Buyukgungor O. J. Coord. Chem., 2009,62:3250-3258
-
[22]
[17] Ding J G, Liu X G, Li B L, et al. Inorg. Chem. Commun., 2008,11:1079-1081
-
[23]
[18] Zhu X, Liu X G, Li B L, et al. CrystEngComm, 2009,11:997-1000
-
[24]
[19] (a)Xu A W, Su C Y, Zhang Z F, et al. New J. Chem., 2001,25: 479-482
-
[25]
(b)Deng H Y, He J R, Pan M, et al. CrystEngComm, 2009, 11:909-917
-
[26]
[20] (a)Gardner G B, Venkataraman D, Moore J S, et al. Nature, 1995,374:792-795
-
[27]
(b)Cheng A L, Ma Y, Zhang J Y, et al. Dalton Trans., 2008, 15:1993-2004
-
[28]
[21] (a)Jain P, Ramachandran V, Clark R J. J. Am. Chem. Soc., 2009,131:13625-13627
-
[29]
(b)YAN Li(闫丽), HAN Pan(韩盼), TIAN Wen-Chao(田文 超), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014, 30:1255-1260
-
[30]
[22] He Y B, Guo Z Y, Xiang S C, et al. Inorg. Chem., 2013,52: 11580-11584
-
[31]
[23] (a)Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
-
[32]
(b)Sheldrick G M. SHELXS-97, Program for Crystal Structure Determination, University of Göttingen, Germany, 1997.
-
[33]
(c)Sheldrick G M. SHELXL-97, Program for the Crystal Structure Refinement, University of Göttingen, Germany, 1997.
-
[34]
[24] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 5th Ed. New York: Wiley & Sons, 1997.
-
[35]
[25] He H, Collins D, Dai F, et al. Cryst. Growth Des., 2010,10: 895-902
-
[36]
[26] Hu T, Bi W, Hu X, et al. Cryst. Growth Des., 2010,10:3324-3326
-
[37]
[27] Zhang X L, Ye B H, Chen X M. Cryst. Growth Des., 2005, 5:1609-1616
-
[38]
[28] (a)Cotton F A, Dikarev E V, Petrukhina M A. Inorg. Chem., 2000,39:6072-6079
-
[39]
(b)Li J, Wang D P, Chen Y G, et al. Z. Anorg. Allg. Chem., 2009,635:2385-2387
-
[40]
[29] Wu S T, Long L S, Huang R B, et al. Cryst. Growth Des., 2007,7:1746-1752
-
[41]
[30] Chen Q, Wang X F, Wang J, et al. Polyhedron, 2014,81: 517-524
-
[42]
[31] Zheng S L, Yang J H, Yu X L, et al. Inorg. Chem., 2004,43: 830-838
-
[43]
[32] Zhang C, Zhang M L, Qin L, et al. Cryst. Growth Des., 2014, 14:491-499
-
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