Citation: WANG Zhao-Dong. Syntheses and Structural Characterization of Copper Complexes with Thioether-Containing Pyridylalkylamide Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2243-2248. doi: 10.11862/CJIC.2015.283
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Thioether-containing pyridylalkylamide ligands 2-(methylsulfanyl)-N-[2-(pyridine-2-yl)methyl]acetamide (HL1) and 2-(methylsulfanyl)-N-[2-(pyridine-2-yl)ethyl]acetamide (HL2) were synthesized and fully characterized. Three copper complexes {[Cu(L1)(CH3OH)](OTf)}n (1), (OTf=triflate), {[Cu(L2)(OTf)]·CH3OH}n (2) and [Cu(HL2)(CH3OH)Cl] (3) were synthesized and characterized with X-ray diffraction methods. The single-crystal X-ray analyses indicate that complex 1 and 2 form 1Dcoordination polymers, while complex 3 is a mononuclear copper complex. The coordination modes of the copper ion are analyzed and the reasons are interpreted.
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[1]
[1] Belle C, Rammal W, Pierre J L. J. Inorg. Biochem., 2005,99: 1929-1936
-
[2]
[2] Kolczak U, Dennison C, Messerschmidt A, et al. Handbook of Metalloproteins. Chichester: Wiley, 2001:1170-1194
-
[3]
[3] Tsukihara T, Aoyama H, Yamashita E, et al. Science, 1995, 269:1069-1074
-
[4]
[4] Brown K, Tegoni M, Prudencio M, et al. Nat. Struct. Biol., 2000,7:191-195
-
[5]
[5] (a)Holland P L, Tolman W B. J. Am. Chem. Soc., 1999,121: 7270-7271
-
[6]
(b)Holland P L, Tolman W B. J. Am. Chem. Soc., 2000,122: 6331-6332
-
[7]
[6] Klein E L, Khan M A, Houser R P. Inorg. Chem., 2004,43: 7272-7274
-
[8]
[7] (a)SMART Software Reference Manual, Bruker-AXS, Madison, WI, 1998.
-
[9]
(b)SAINT Software Reference Manual, Bruker-AXS, Madison, WI, 1998.
-
[10]
[8] Sheldrick G M. SADABS, University of Göttingen, Germany, 2002.
-
[11]
[9] (a)Sheldrick G M. SHELXTL Version 6.10 Reference Manual, Bruker-AXS, Madison, WI, 2000.
-
[12]
(b)International Tables for Crystallography, Boston MA, Kluwer, 1995.
-
[1]
-
-
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