Citation: YANG Xiao-Xun, LENG Ji-Dong, LIU Jun-Liang, JIA Jian-Hua, TONG Ming-Liang. Synthesis, Structures and Magnetic Properties of Two Tetranuclear and Decanuclear Manganese Clusters Bearing the Multidentate Schiff-Base Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1831-1838. doi: 10.11862/CJIC.2015.260
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A multidentate salicylaldehyde Schiff-base ligand with {NO4} donor set, 3, 5-di-tert-butylsalicylaldehyde-trihydroxymethylaminomethane (H4L), has been synthesized for the first time and characterized by elemental analysis, IR and 1H NMR. Solution reactions of Mn(ClO4)2 or MnCl2·4H2O with H4L in air generated a tetranuclear complex [MnIII4(HL)2(H2L)2(MeCN)4](ClO4)2·2MeCN (1) and a decanuclear complex [MnIII6MnII4(bz)10(L)4(H2O)2]·10MeCN (2), respectively. X-ray studies reveal that complex 1 crystallizes in triclinic space group P1, while complex 2 crystallizes in orthorhombic space group Aba2. Magnetism data in the temperature range 2~300 K have been carried out, indicating the presence of the antiferromagnetic interaction within 2.
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-
[1]
[1] Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993,115:1804-1816
-
[2]
[2] Sessoli R, Gatteschi D, Caneschi A, et al. Nature, 1993,365:141-143
-
[3]
[3] Aromí G, Brechin E K. Struct. Bond., 2006,122:1-67
-
[4]
[4] Friedman J R, Sarachik M P. Annu. Rev. Condens. Matter Phys., 2010,1:109-128
-
[5]
[5] Gatteschi D, Sessoli R. Angew. Chem. Int. Ed., 2003,42:268-297
-
[6]
[6] Christou G, Gatteschi D, Hendrickson D N, et al. MRS Bull., 2000,25:66-71
-
[7]
[7] Ako A M, Hewitt I J, Mereacre V, et al. Angew. Chem. Int. Ed., 2006,45:4926-4929
-
[8]
[8] Manoli M, Prescimone A, Bagai R, et al. Inorg. Chem., 2007, 46:6968-6979
-
[9]
[9] Moushi E E, Lampropoulos C, Wernsdorfer W, et al. Inorg. Chem., 2007,46:3795-3797
-
[10]
[10] Murugesu M, Raftery J, Wernsdorfer W, et al. Inorg. Chem., 2004,43:4203-4209
-
[11]
[11] Rumberger E M, Shah S J, Beedle C C, et al. Inorg. Chem., 2005,44:2742-2752
-
[12]
[12] YAO Hong-Chang(要红昌), WANG Ning(王宁), LI Miao-Miao(李淼淼), et al. J. Zhengzhou Univ.:Nat. Sci. Ed. (郑州大学学报:理学版), 2008,40:88-94
-
[13]
[13] WANG Peng-Fei(汪鹏飞), WANG Xin(汪新), WU Guang-Hui(伍光辉), et al. Chinese J. Inorg. Chem. (无机化学学报), 2011,27:1881-1886
-
[14]
[14] ZHOU Ai-Ju(周爱菊), LIANG Jing-Jing(梁晶晶), ZHENG Yan-Zhen(郑彦臻), et al. Chinese J. Inorg. Chem. (无机化学学报), 2012,28:2425-2430
-
[15]
[15] Fontecha J B, Goetz S, McKee V. Dalton Trans., 2005:923-929
-
[16]
[16] Oshio H, Hoshino N, Ito T, et al. J. Am. Chem. Soc., 2004, 126:8805-8812
-
[17]
[17] Oshio H, Hoshino N, Ito T, et al. Angew. Chem. Int. Ed., 2003,42:223-225
-
[18]
[18] Oshio H, Nihei M, Yoshida A, et al. Chem. Eur. J., 2005, 11:843-848
-
[19]
[19] Oshio H, Nakano M. Chem. Eur. J., 2005,11:5178-5185
-
[20]
[20] Bagai R, Abboud K A, Christou G. Dalton Trans., 2006:3306-3312
-
[21]
[21] Hoshiko J A, Wang G, Ziller J W, et al. Dalton Trans., 2008:5712-5714
-
[22]
[22] Sheldrick G M. SADABS, University of Göttingen, Germany, 2002.
-
[23]
[23] Sheldrick G M. Acta Crystallogr., 2008,A64:112-122
-
[24]
[24] Hewitt I J, Tang J K, Madhu N T, et al. Chem. Commun., 2006:2650-2652
-
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