Citation: NASEN Bate, CHEN Wei-Lin, LIU Zhu-Jun, XU Sha-Sha, WANG En-Bo. Four Keggin-Based Nanomaterials: Synthesis and Adsorption of Organic Dyes[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1820-1826. doi: 10.11862/CJIC.2015.246
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Four Keggin-based nanomaterials (PMo12b, PW12b, SiW12b and GeW12b) were controllably prepared. The structure and the size of all the compounds have been characterized by IR, UV-Vis, XRD and SEM. Further investigations showed that four Keggin-based nanomaterials exhibited fast adsorption rate towards dye molecules. The adsorption efficiency of those compounds (100 mg) towards MB (100 mL of 20 mg·L-1) could reach up to 96.3% in the initial 5 min under dark condition, the adsorption efficiency sequence is PMo12b > PW12b > GeW12b > SiW12b. And also, the adsorption efficiency towards RhB (100 mL of 20 mg·L-1)could reach up to 96.1% in 30 min under same conditions, the adsorption efficiency sequence is PW12b > PMo12b > SiW12b > GeW12b. All the investigations indicate that the four kind of POMs-nanomaterials present excellent adsorption properties of the organic dyes.
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