Citation: YANG Hong, HAN Xin-Li. Syntheses, Crystal Structures and Cleavage Mechanism of C-S Bond in Cd(Ⅱ) and Zn(Ⅱ) Complexes with Tris(2-mercaptopyridyl) methane[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1597-1602. doi: 10.11862/CJIC.2015.217
-
Two complexes of Cd(Ⅱ) or Zn(Ⅱ) with L (L=tris(2-mercaptopyridyl)methane), Cd(L)4(NO3)2 (1) and Zn(L)4(ClO4)2 (2), have been synthesized and characterized. The cleavage of the C-S bonds of the ligand has been discovered and the cleavage mechanism has been studied by UV-Vis titration and GC-MS. The possible reaction mechanism has been proposed. Single crystal X-ray analyses show that the Cd and Zn atoms are all in a four-coordinated distorted tetrahedron environment. The intermolecular π-π stacking action extends the complex 1 to a 2D net work. CCDC: 627210, 1; 644051, 2.
-
-
[1]
[1] LI Yong-Qiang(李永强), CHEN Xu(陈煦), ZHANG He(张和), et al. Tianjin Chem. Ind.(天津化工), 2000(4):23-24
-
[2]
[2] Hong W S, Weng M J, Cao R, et al. Angew. Chem. Int. Ed., 2000,39:2911-2914
-
[3]
[3] Lobana T S, Sharma R, Sharma R, et al. Inorg. Chem., 2005, 44:1914-1921
-
[4]
[4] Chen X D, Wu H F, Du M. Chem. Commun., 2008,11:1296-1298
-
[5]
[5] Li D, Wu T. Inorg. Chem., 2009,44:1175-1177
-
[6]
[6] Li D, Wu T, Zhou X P, et al. Angew. Chem. Int. Ed., 2005, 44:4175-4178
-
[7]
[7] Song J L, Dong Z C, Zeng H Y, et al. Inorg. Chem., 2003, 42:2136-2139
-
[8]
[8] Cheng J K, Chen Y B, Wu L, et al. Inorg. Chem., 2005,44:3386-3390
-
[9]
[9] de Castro V D, de Lima G M, Filgueiras C A L, et al. J. Mol. Struct., 2002,609:199-203
-
[10]
[10] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
-
[11]
[11] Sheldrick G M. SHELXL-97, Program for Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
-
[12]
[12] Ma A Q, Zhu L G. Transition Met. Chem., 2005,30:869-872
-
[13]
[13] SHI Xiu-Min(石秀敏), JIANG Rui(姜锐), SONG Wei(宋薇), et al. Spectrosc. Spectral Anal.(光谱学与光谱分析), 2012, 32(6):1588-1591
-
[14]
[14] GUO Xiao-Nan(郭晓楠), DU Rui(杜蕊), ZHAO Yan-Ying (赵彦英), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2012, 28(7):1570-1578
-
[15]
[15] Lima M C P, Coutinho K, Canuto S, et al. J. Phys. Chem. A, 2006,110:7253-7261
-
[16]
[16] LI Yan-Rong(李艳荣), GUO Yong-Min(国永敏), LI Bao-Zong(李宝宗). Chem. Res.(化学研究), 2006,32(6):71-73
-
[17]
[17] XIAO Ling-Mei(萧岭梅), GAO Hong-He(高红核), GUO Xin(郭欣), et al. J. Capital Normal University(首都师范大学学报), 2002,23(4):44-49
-
[18]
[18] Gavin D, Alexander Z, Benjamin W R, et al. Organometallics, 2011,30(2):5844-5850
-
[1]
-
-
[1]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[2]
Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO2 methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
-
[3]
Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
-
[4]
Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoSx assembled from [Mo3S13]2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
-
[5]
Qianqian Liu , Xing Du , Wanfei Li , Wei-Lin Dai , Bo Liu . Synergistic Effects of Internal Electric and Dipole Fields in SnNb2O6/Nitrogen-Enriched C3N5 S-Scheme Heterojunction for Boosting Photocatalytic Performance. Acta Physico-Chimica Sinica, 2024, 40(10): 2311016-. doi: 10.3866/PKU.WHXB202311016
-
[6]
Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
-
[7]
Lei Wan , Yizhou Tong , Xi Lu , Yao Fu . Cobalt-catalyzed reductive alkynylation to construct C(sp)-C(sp3) and C(sp)-C(sp2) bonds. Chinese Chemical Letters, 2024, 35(7): 109283-. doi: 10.1016/j.cclet.2023.109283
-
[8]
Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
-
[9]
Kangmin Wang , Liqiu Wan , Jingyu Wang , Chunlin Zhou , Ke Yang , Liang Zhou , Bijin Li . Multifunctional 2-(2′-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs. Chinese Chemical Letters, 2024, 35(10): 109554-. doi: 10.1016/j.cclet.2024.109554
-
[10]
Jiao Li , Chenyang Zhang , Chuhan Wu , Yan Liu , Xuejian Zhang , Xiao Li , Yongtao Li , Jing Sun , Zhongmin Su . Defined organic-octamolybdate crystalline superstructures derived Mo2C@C as efficient hydrogen evolution electrocatalysts. Chinese Chemical Letters, 2024, 35(6): 108782-. doi: 10.1016/j.cclet.2023.108782
-
[11]
Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
-
[12]
Bin Fang , Jiaqi Yang , Limin Wang , Haoqin Li , Jiaying Guo , Jiaxin Zhang , Qingyuan Guo , Bo Peng , Kedi Liu , Miaomiao Xi , Hua Bai , Li Fu , Lin Li . A mitochondria-targeted H2S-activatable fluorogenic probe for tracking hepatic ischemia-reperfusion injury. Chinese Chemical Letters, 2024, 35(6): 108913-. doi: 10.1016/j.cclet.2023.108913
-
[13]
Jia-Mei Qin , Xue Li , Wei Lang , Fu-Hao Zhang , Qian-Yong Cao . An AIEgen nano-assembly for simultaneous detection of ATP and H2S. Chinese Chemical Letters, 2024, 35(6): 108925-. doi: 10.1016/j.cclet.2023.108925
-
[14]
Bicheng Zhu , Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327
-
[15]
Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
-
[16]
Jiajun Wang , Guolin Yi , Shengling Guo , Jianing Wang , Shujuan Li , Ke Xu , Weiyi Wang , Shulai Lei . Computational design of bimetallic TM2@g-C9N4 electrocatalysts for enhanced CO reduction toward C2 products. Chinese Chemical Letters, 2024, 35(7): 109050-. doi: 10.1016/j.cclet.2023.109050
-
[17]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[18]
Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
-
[19]
Yi Liu , Zhe-Hao Wang , Guan-Hua Xue , Lin Chen , Li-Hua Yuan , Yi-Wen Li , Da-Gang Yu , Jian-Heng Ye . Photocatalytic dicarboxylation of strained C–C bonds with CO2 via consecutive visible-light-induced electron transfer. Chinese Chemical Letters, 2024, 35(6): 109138-. doi: 10.1016/j.cclet.2023.109138
-
[20]
Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(206)
- HTML views(22)