Citation: YUE Cui-Min, GAO Dong-Zhao, WANG Xiu-Guang. Syntheses, Crystal Structures and Properties of a Series of Helical Complexes Constructed by Flexible N,N'-Bis(3-pyridylmethyl)amine[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1609-1618. doi: 10.11862/CJIC.2015.213
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Five helical coordination polymers {[Cu(Hbpma)(H2O)4]2(SO4)3·3.5H2O}n (1), {[Ni(Hbpma)(H2O)4]4(SO4)6·10.75H2O}n (2), {[Mn(Hbpma)(H2O)4](SO4)1.5·3H2O}n (3), {[Zn(Hbpma)(H2O)4]4(SO4)6·4H2O·4CH3OH}n (4) and {[Cu(Hbpma)2(H2O)2](SO4)2·9H2O}n (5) (bpma=N,N'-bis(3-pyridylmethyl)amine) were synthesized and structurally char-acterized. The single-crystal X-ray analyses indicate that complexes 1~4 crystallize in the one-dimensional chain structures and complex 5 shows the two-dimensional layer structure, in which the metal ions are bridged by the protonated bpma ligands. It is noted that the flexible bpma ligands with the trans-trans conformation lead to the pseudo-helical chains for complexes 1~2, the helical chains for complexes 3~4 and a helical layer for complex 5. The magnetic properties and the thermal behavior are investigated. CCDC: 966929, 1; 966932, 2; 966930, 3; 966931, 4; 1054736, 5.
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