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Citation: BAI Shu-Ming, TIAN Jian-Hua, MA Huan-Mei, ZHU Kun-Lei, SHAN Zhong-Qiang. Preparation and Photoelectric Performance of Mn-Doped-CdSSe2 Quantum Dots Sensitized Electrode[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1365-1372. doi: 10.11862/CJIC.2015.197 shu

Preparation and Photoelectric Performance of Mn-Doped-CdSSe2 Quantum Dots Sensitized Electrode

  • 1.

    1 School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;

  • 2.

    2 Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin University, Tianjin 300072, China

  • Corresponding author: TIAN Jian-Hua, 
  • Received Date: 24 March 2015
    Available Online: 21 May 2015

    Fund Project: 国家973项目基金(No.2015CB251100)资助项目。 (No.2015CB251100)

  • Sodium sulfide-selenium prepared by adding Se powder into the Na2S methanol-water solution was used as the anionic precursor, and the methanol-water solution of Cd(NO3)2 and Mn(CH3COO)2 was used as the cationic precursor, respectively. Then, cadmium sulfide-selenium quantum dots sensitized TiO2 photoanodes (CdSSe2/TiO2) and Mn2+ doped cadmium sulfide-selenium quantum dots sensitized TiO2 photoanodes (Mn-CdSSe2/TiO2) were successfully prepared by the successive ionic layer adsorption and reaction (SILAR) for Quantum dots solar cell (QDSC). The Raman spectrum, XPS were applied to analyze the chemical bonds of the Na2SSe2 precursors. EDX and UV-Vis were investigated the composition and light absorption property of Mn-CdSSe2/TiO2 photoanode. J-V curves and IPCE were used to characterize photovoltaic performance of the as-prepared CdS/TiO2, CdSSe2/TiO2 and Mn-CdSSe2/TiO2 photoanodes. The results reveals that the Mn-CdSSe2/TiO2 photoanode with enhanced energy conversion efficiency has been fabricated by SILAR method using the anionic precursors prepared with 0.12 mol·L-1 Se and 0.5 mol·L-1 Na2S, the cationic precursor of 0.5 mol·L-1 Cd2+ and 0.3 mol·L-1 Mn2+. Compared with the CdSSe2/TiO2 and CdS/TiO2 photoanodes, the efficiency of the Mn-CdSSe2/TiO2 photoanode is increased by 90% and 247%, separately.
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