Citation: WANG Ying, XUE Bing, LI Yi-Lin, LI Si-Nan, XU Chong-Fu. Extensive Hydrosilation of Acetyl Manganese Pentacarbonyl[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1393-1401. doi: 10.11862/CJIC.2015.194
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(CO)5MnCOCH3 (1) was synthesized in two steps. A solution 1 with Me2PhSiH in C6D6 was continuously monitored by 1H NMR spectroscopy for 9 h and reaction profile was established using timely contents (mmol) obtained by directly integrating chemical labels of the reactants and derivatives against that of the internal standard C6H5(CH2)2C6H5. 9 intermediates and final products emerged in the extensive hydrosilation were prepared and the molecular structures of the derivations generated in the reaction process were positively confirmed by comparison of their NMR spectra with that of real substances. All besides the 6 species that were quantified by direct integration of their chemical labels the other 3 were indirectly quantified by combination of chemical stoichiometry and integration of their chemical labels. Attempt was made to make plausible explanations for the origins of these species. Finally, a mechanism with multiple step reactions process and double pathways was proposed. More than 90.7% of the total manganese source was accounted for at 9 h and meanwhile that of more than 91.4% of the total silicon source was accounted for.
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-
[1]
[1] Gregg B T, Hanna P K, Crawford E J, et al. J. Am. Chem. Soc., 1991, 113(47):384-385
-
[2]
[2] Hanna P K, Gregg B T, CutlerA R. Organometallics, 1991, 10(1):31-33
-
[3]
[3] Ziegler T, Verslius L, Tschinke V J. J. Am. Chem. Soc., 1986, 108(21):612-614
-
[4]
[4] Axe F U, Marynick D S. Organometallics, 1987, 6(17):572-575
-
[5]
[5] Wegman R W. Organometallics, 1986, 5(3):707-710
-
[6]
[6] Kovacs I, Sisak A, Ungvary F, et al. Organometallics, 1988, 7 (10):1025-1029
-
[7]
[7] Glaysz J A. Acc. Chem. Res., 1984, 17(57):326-330
-
[8]
[8] Selover J C, Vaughn G D, Strouse C E, et al. J. Am. Chem. Soc., 1986, 108(11):1455-1457
-
[9]
[9] Vaughn G D, Glaysz J A. J. Am. Chem. Soc., 1986, 108(35): 1473-1475
-
[10]
[10] Gregg B T, Cutler A R. J. Am. Chem. Soc., 1996, 118, 42 (19):10069-10084
-
[11]
[11] Krein K A, Gladysz J A. Organometallics, 1986, 5(15):936-940
-
[12]
[12] Mars M, Brinkman K C, Lisensky C A, et al. J. Org. Chem., 1985, 50(24):3396-3398
-
[13]
[13] XU Chong-Fu(徐崇福), FANG Jun-Zhuo(房俊卓), CHEN Miao(陈苗), et al. Acta Chim. Sin.(化学学报), 2008, 66(10): 1239-1244
-
[14]
[14] Gregg B T, Cutler A R. Organometallics, 1994, 13(9):1039-1043
-
[15]
[15] XU Chong-Fu(徐崇福), FANG Jun-Zhuo(房俊卓), XUE Bing (薛冰), et al. Acta Chim. Sin.(化学学报), 2011, 69(8):999-1006
-
[16]
[16] Gladysz J A, Williams G M, Tam W, et al. Inorg. Chem., 1979, 18(3):553-558
-
[17]
[17] Warner K E, Norton J R. Organometallics, 1985, 4(16):2150-2154
-
[18]
[18] Tan K Y D, Teng G F, Fan W Y. Organometallics, 2011, 30 (15):4136-4143
-
[19]
[19] Anderson G K. Acc. Chem. Res., 1984, 17(21):67-74
-
[20]
[20] Gregg B T, Cutler A R. Organometallics, 1998, 17(32):4169-4175
-
[21]
[21] Gray L M, Donald A T. Inorganic Chemistry. New Jersey: Prentice Hall, 1999:297
-
[22]
[22] Gregg B T, Cutler A R. J. Am. Chem. Soc., 1995, 117(10): 10139-10140
-
[23]
[23] Mao Z, Gregg B T, Cutler A R. Organometallics, 1998, 17(10): 1993-2002
-
[24]
[24] Green M L H, Nagy P L I. J. Organomet. Chem., 1963, 1(27): 58-60
-
[25]
[25] Xu C F, Anderson G K A. Organometallics, 1996, 15(7):1760-1764
-
[26]
[26] XU Chong-Fu(徐崇福), FANG Jun-Zhuo(房俊卓), XUE Bing (薛冰), et al. Acta Chim. Sin.(化学学报), 2009, 67(20):2355-2362
-
[27]
[27] LI Rong (厉荣), CHEN Peng-Gang(陈鹏刚). Chinese J. Inorg. Chem.(无机化学学报), 2008, 24(20):657-660
-
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