Citation: ZHANG Lu, ZENG Su-Yuan, LIU Tao, SUN Jun-Shan, DOU Jian-Min, JIANG Jian-Zhuang. Mixed Tetrapyrrole Terbium Triple-Decker Single Molecule Magnets with Bulky Inorganic Polyhedral Oligomeric Silsesquioxanes Moieties at Outer Porphyrin Peripheries[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(9): 1761-1773. doi: 10.11862/CJIC.2015.190
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Bulky inorganic polyhedral oligomeric silsesquioxanes (POSS) moieties were introduced onto the porphyrin periphery in mixed (phthalocyaninato) (porphyrinato) terbium molecule, giving POSS-involved hybrid triple-decker complex Tb2(Pc)[T(OPOSS)4PP]2 (1) [H2Pc=phthalocyanine; H2T(OPOSS)4PP=5, 10, 15, 20-tetra{[[N-[heptakis(isobutyl)propoxy]phenyl]octasiloxane]}porphyrin]. For comparative study, triple-decker analogue Tb2(Pc)(TPP)2 (2) (H2TPP=5, 10, 15, 20-tetraphenyporphyrin) was also prepared and structurally characterized. In particular, Tb2(Pc)[T(OPOSS)4PP]2 (1) and Tb2(Pc)(TPP)2 (2) were revealed to display intrinsic single molecule magnet (SMM) and non-SMM (or field-induced) characteristic, respectively, at zero Oe (or a 3.0 Oe ac field), clearly indicating the effect of the covalently linked, homogenously dispersed POSS moieties on effectively separating the magnetic cores and improving the magnetic property of triple-decker compounds.
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