Citation: CHEN Hong, YU Min, LIU Guang-Xiang. Syntheses and Crystal Structures of Nickel(Ⅱ) and Cadmium(Ⅱ) Coordination Polymers Constructed by Benzene-1,4-dioxydiacetate and 4,4-Bis(imidazole-l-yl)diphenyl Ether[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1261-1268. doi: 10.11862/CJIC.2015.170
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Two coordination polymers, [Ni(BDOA)(BIDPE)(H2O)]n (1) and [Cd(BDOA)0.5(BIDPE)Cl]n (2), (H2BDOA=benzene-1,4-dioxydiacetic acid and BIDPE=4,4'-bis(imidazole-l-yl)diphenyl ether), have been synthesized and characterized by IRspectroscopy, elemental analysis and single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P1 with a=0.93497(8) nm, b=1.03231(9) nm, c=1.35291(12) nm, α=96.3980(10)°, β=90.7290(10)°, γ=102.0270(10) °, V=1.26831(19) nm3, Z=2, Mw=603.22, Dc=1.580 g·cm-3, μ=0.827, F(000)=624, R1=0.0395, wR2=0.0895(I>2σ(I)). Complex 2 belongs to triclinic, space group P1 with a=1.01751(7) nm, b=1.04299(7) nm, c=1.17338(8) nm, α=68.7230(10)°, β=71.8260(10)°, γ=76.0910(10)°, V=1.09105(13) nm3, Z=2, Mw=562.26, Dc=1.711 g·cm-3, μ=1.163, F(000)=562, R1=0.0210, wR2=0.0537(I>2σ(I)). Structural analyses reveal that complex 1 exhibits a two-dimensional (2D) corrugated layer structure, whereas complex 2 possesses a one-dimensional (1D) chain structure which is generated by joining binuclear Cd2 units by BIDPEand BDOAligands. The results show that the nature of metal ions plays an important role in governing the molecular frameworks. The photochemical properties of two complexes have also been studied.
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