Citation: QIAO Yu, MA Bo-Nan, LI Xiu-Ying, ZHANG Xing-Jing, WEI Bing, HOU Jing, CHE Guang-Bo. Cd(Ⅱ) Complexes Based on 2-(Pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic Acid Ligand: Crystal Structures and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1245-1251. doi: 10.11862/CJIC.2015.168
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Two cadmium(Ⅱ) complexes based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid (H3PIDC) and 1,10-phenanthroline's derivatives mixed ligands, namely, {[Cd3(HPIDC)3(DPPZ)3]·7H2O}n (1) and [Cd(HPIDC)(Imphen)(H2O)]2 (2) (DPPZ=dipyrido[3,2-a:2',3'-c]phenazine, Imphen=imidazo[4,5-f ][1,10]phenanthroline), have been synthesized under hydrothermal conditions and characterized by elemental analysis, infrared spectrum and single-crystal X-ray diffraction. Complexes 1 and 2 are one-dimensional chain and zero-dimensional structures, respectively. Two complexes exhibit excellent thermal stabilities and photoluminescent properties.
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