Citation: YANG Li, WANG Hua, LI Kong-Zhai, WEI Yong-Gang, ZHU Xing. Microwave-Assisted Synthesis of Ru(Ⅱ) Complex and Self-Assembled Multilayer Film Formed by Alternating Layers of the Ru Complex[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1131-1138. doi: 10.11862/CJIC.2015.151
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Asymmetrical ruthenium complex bearing phosphonic acid was prepared under the microwave irradiation and fully characterized by 1H NMR, ESI-MS and thermo gravimetric(TG) analysis. For the Ru complex, the phosphonic groups were selectively attached to the ITO through covalent interaction, resulting in the hydrophilic surface due to the appearance of the exposed other phosphonic-acid groups on the top. The Layer by layer(LBL) growth of molecular units was used to fabricate redox-active films of Ru complex, which was followed by the formation of Zr4+-phosphonate layer. The buildup of the films was followed by monitoring cyclic voltammetry(CV) and ultraviolet-visible absorption spectrometry(UV-Vis) measurements. The results showed the electrode modified by multilayered film displayed reversible redox processes, and the Ru(Ⅱ/Ⅲ) oxidative peak was observed at +0.53 V. The plots of surface coverage versus number of layers show a linear relationship, which means a uniform layer structure is formed during the LBL process. UV-Vis spectra shows the prepared Ru film have strong absorptions between 300 nm and 600 nm. These findings show the Ru complex has good photoelectric properties.
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-
[1]
[1] Desilvestro J, Grätzel M, Kavan L, et al. J. Am. Chem. Soc., 1985,107:2988-2990
-
[2]
[2] O'Regan B, Grtzel M. Nature, 1991,352:737-740
-
[3]
[3] Vougioukalakis G, Philippopoulos A, Stergiopoulos T. Coord. Chem. Rev., 2011,255:2602-2621
-
[4]
[4] Wang P, Zakeeruddin S M, Moser J E, et al. Nat. Mater., 2003,2:402-407
-
[5]
[5] Gao S Y, Li X, Yang C P, et al. J. Solid State Chem., 2006, 179:1407-1414
-
[6]
[6] JIANG Cai-Wu(蒋才武), CHAO Hui(巢晖), LI Run-Hua(李 润华), et al. Acta Chim. Sinica(化学学报), 2002,60:65-70
-
[7]
[7] Sussuehi E M, Lima A A, Giovani W F. Polyhedron, 2006, 25:1457-1463
-
[8]
[8] GUO Chui-Lian(郭翠莲), WU Yue(吴悦), ZHOU Yi-Ming(周 益明), et al. Chinese J. Inorg. Chem.(无机化学学报), 2007, 10:1771-1776
-
[9]
[9] SHAO Hui-Bo(邵会波), YU Hua-Zhong(于化中), ZHANG Hao-Li(张浩力), et al. Acta Phys.-Chim. Sin.(物理化学学 报), 1998,14:772-777
-
[10]
[10] Mezzenga R, Ruokolainen J, Fredrickson G H, et al. Scince, 2003,299:1872-874
-
[11]
[11] Parak W J. Science, 2011,334:1359-1360
-
[12]
[12] ZHANG Yu-Qi(张玉琦), GAO Li-Hua(高丽华), DUAN Zhi-Ming(段智明), et al. Acta Chim. Sinica(化学学报), 2004, 62:738-741
-
[13]
[13] Li S, Li J, Chen S, et al. Mater. Chem. Phys., 2013,142:513 -520
-
[14]
[14] WANG Cheng(王程), SHI Hui-Dheng(施惠生), LI Yan(李 艳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011, 27:2239-2244
-
[15]
[15] Dubey A, Mishra A, Min J, et al. Inorg. Chim. Acta, 2014, 423:326-331
-
[16]
[16] Schmitt J, Raatz A, Dietrich F, et al. CIRP Ann-Manuf. Technol., 2014,63:9-12
-
[17]
[17] Yang S, Jin X, Liu K S. Particuology, 2013,11:361-370
-
[18]
[18] Park S, Lim J H, Chung S W, et al. Science, 2004,303:348-351
-
[19]
[19] Du Y, Wei H, Kang J Z, et al. Anal. Chem., 2005,77:7993-7993
-
[20]
[20] Fukuda N, Mitsuishi M, Aoki A, et al. J. Phys. Chem. B, 2002,106:7048-7052
-
[21]
[21] Decher G. Science, 1997,277:1232-1237
-
[22]
[22] Geneste F, Moinet C. J. Electroanal. Chem., 2006,594:105-110
-
[23]
[23] He P, Bayachou M. Langmuir, 2005,21:6086-6092
-
[24]
[24] Pinheiro S O, Deousa J R, Santiago M O, et al. Inorg. Chim. Acta, 2006,359:391-401
-
[25]
[25] Lahav M, Heleg Shabtai V, Wasserman J, et al. J. Am. Chem. Soc., 2000,122:11480-11487
-
[26]
[26] Zhou Y,Yan D. Chem. Commun., 2009,10:1172-1188
-
[27]
[27] Hong H G, Mallouk T E. Langmuir, 1991,7:362-2369
-
[28]
[28] Donley C, Dunphy D, Paine D, et al. Langmuir, 2001,18: 450-457
-
[29]
[29] Kobayashi K, Tonegawa N, Fujii S, et al. Langmuir, 2008, 24:13203-13211
-
[30]
[30] Erten-Ela S, Sogut S, Ocakoglu K. Mater. Sci. Semicond. Process., 2014,23:159-166
-
[31]
[31] Kalyanasundaram K, Nazeeruddin M K, Gritzel M. Inorg. Chim. Acta, 1992,198:831-839
-
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