Citation: ZHANG Shu-Fang, XIONG Fang, LIU Yu-Fen, HE Zhan, LIANG Yue, XUE Jun-ru, JING Lin-Hai, QIN Da-Bin. Syntheses and Structures of Two 3D Metal NHCs Based on Flexible Functionalized Bibenzimidazole[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 1027-1033. doi: 10.11862/CJIC.2015.147
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[Hg(C32H28N4O)](CH3COO)(PF6)2 (1) and [NiCl(C30H28N6O)]PF6 (2) have been synthesized based on1,1'-bisbenzyl-3,3'-oxybis(ethane-2,1-diyl)-dibenzimidazolium-dihexafluorophosphate ligand (L1) and 1,1'-bis (pyridine-2-ylmethyl)-3,3'-oxybis(ethane-2,1-diyl)-dibenzimidazolium-dihexafluorophosphate ligand (L2) and structurally characterized. The complex 1 is a rare three valence state mercury NHC and crystallizes in the P21/c space group with monoclinic crystal system. The complex 2 crystallizes in the P21/n space group with monoclinic crystal system. There are O-H…F, C-H…F, C-H…Cl, C-H…π, P-F…π hydrogen bonds interactions and π…π stacking interactions contributing to 3D supramolecular structure of 1 and 2.
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