Citation: DUAN Yan-Lin, MA Ran-Ran, CAO Ting-Ting, LIU Ting, LI Cheng-Juan, WANG Su-Na. Two Unusual 2D→3D Entanglement Networks Self-Assembled from a T-shaped Tricarboxylate Ligand: Syntheses, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1231-1238. doi: 10.11862/CJIC.2015.132
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Two Ni(Ⅱ)-organic frameworks, namely, {[Ni3(BPT)2(bpe)2(H2O)6]·2DMF·7H2O}n (1) and {[Ni3(BPT)2(bpea)2(H2O)6]·2DMF·5H2O}n (2) (H3BPT = biphenyl-3,4',5-tricarboxylic acid, bpe = 1,2-bis(4-pyridyl)ethylene, bpea=1,2-bis(4-pyridyl)ethane, DMF=N,N-dimethylformamide), were solvothermally synthesized and characterized. In the two isostructural complexes, BPTligand and N-containing ligand bpea or bpe connect adjacent Ni centers to form a bilayer structure. The whole topology could be represented as (3,4)-connected (63)(65.8) with the tricarboxylate ligands and Ni atoms as 3-connected T-shaped and 4-connected tetrahedral nodes, respectively. Each bilayer polycatenates two other identical bilayers, giving rise to a 2D→3D polycatenating network with polyrotaxane moieties. Gas adsorptive measurements indicated compound 1 exhibited adsorption of CO2 and N2.
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