Citation: WANG Peng, CHEN Shang-Xing, HUANG Min, ZHAO Zhen-Dong, WANG Zong-De, FAN Guo-Rong. Synthesis of Ordered Supermicroporous Silica Using Rosin-Based Quaternary Ammonium Salt[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 767-773. doi: 10.11862/CJIC.2015.105
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Ordered hexagonal supermicroporous silica with nanosheet morphology was successfully synthesized using rosin-based quaternary ammonium salt (dehydroabietyltrimethyl ammonium bromine, short for DTAB) as template agent, tetraethyl orthosilicate as silicate source, and ammonia as alkaline medium. XRD, N2 adsorption-desorption, TEM, and SEM were used to characterize the samples. The results indicated that the dosage amount of template agent, silicate source, alkaline medium, crystallization temperature and stirring time had great effects on the regularity of the pore structure. When the mole ratio of nSiO2:nDTAB:nNH3:nH2O was 1.0:0.1:11.3:924.0; crystallization temperature was 373 K; stirring time was 24 h, the sample got the hightest regularity. After the calcination, the synthesized material possessed large surface area (1 024 m2·g-1), high pore volume (0.56 cm3·g-1) and narrow pore size distribution (centered at about 1.80 nm).
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