Citation: KANG Jing-Yan, HUANG Shi-Jie, ZHAO Xiu-Hua, ZHAO Ya-Yun, LI Xing. Syntheses, Crystal Structures and Fluorescent Properties of Two Zn(Ⅱ) Complexes Based on Sulfaquinoxalines[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 798-806. doi: 10.11862/CJIC.2015.097
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Two Zn(Ⅱ) compounds, [Zn(L)2(phen)]·H2O (1) and {[Zn(L)2(bpy)]·2EtOH}n (2) (L=sulfaquinoxaline, phen=phenanthroline, bpy=4,4'-bipyridine)have been synthesized and characterized by single crystal X-ray diffraction, thermal analysis, elemental analysis, IR, UV-Vis and fluorescence. Single crystal X-ray diffraction reveals that complex 1 is a mononuclear structure and complex 2 is one-dimensional structure. Thermal analyses show that complex 1 and 2 have high thermal stability. CCDC: 991934, 1; 991935, 2.
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