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Citation: KANG Jing-Yan, HUANG Shi-Jie, ZHAO Xiu-Hua, ZHAO Ya-Yun, LI Xing. Syntheses, Crystal Structures and Fluorescent Properties of Two Zn(Ⅱ) Complexes Based on Sulfaquinoxalines[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 798-806. doi: 10.11862/CJIC.2015.097 shu

Syntheses, Crystal Structures and Fluorescent Properties of Two Zn(Ⅱ) Complexes Based on Sulfaquinoxalines

  • 1.

    1 Faculty of Science, Ningbo University, Ningbo, Zhejiang 315211, China;

  • 2.

    2 Beilun entry-exit inspection and Quarantine Bureau of P.R.C, Ningbo, Zhejiang 315800, China

  • Received Date: 12 October 2014
    Available Online: 5 January 2015

    Fund Project: 国家自然科学基金(No.20971075) (No.20971075)宁波市基金(No.2014A610106、2014C50037) (No.2014A610106、2014C50037)浙江省新苗人才计划项目(No.2013R405068) (No.2013R405068)浙江省省级重点企业研究院青年科学家培养计划(No.2013R40009) (No.2013R40009)宁波大学研究生优秀学位论文培育基金(No.py2013001) (No.py2013001)

  • Two Zn(Ⅱ) compounds, [Zn(L)2(phen)]·H2O (1) and {[Zn(L)2(bpy)]·2EtOH}n (2) (L=sulfaquinoxaline, phen=phenanthroline, bpy=4,4'-bipyridine)have been synthesized and characterized by single crystal X-ray diffraction, thermal analysis, elemental analysis, IR, UV-Vis and fluorescence. Single crystal X-ray diffraction reveals that complex 1 is a mononuclear structure and complex 2 is one-dimensional structure. Thermal analyses show that complex 1 and 2 have high thermal stability. CCDC: 991934, 1; 991935, 2.
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