Citation: LIU Ying-Chun, MA Zhi-Hong, SHANG Cheng-Xi, HAN Zhan-Gang, ZHENG Xue-Zhong, LIN Jin. Ruthenium Carbonyl Complexes Containing Alkyl-Substituted Indenyl Ligands: Syntheses and Structures[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 774-780. doi: 10.11862/CJIC.2015.088
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Reactions of the alkyl-substituted indenyl ligands [C9H7R] (R=CH2CH2CH3 (1), CH(CH3)2 (2), C5H9 (3), CH2C6H5 (4), CH2CH=CH2 (5)) with Ru3(CO)12 in refluxing xylene or heptane gave the responding dinuclear metal carbonyl complexes [(η5-C9H6R)Ru(CO)(μ-CO)]2 (R=CH2CH2CH3 (6), CH(CH3)2 (7), C5H9 (8), CH2C6H5 (9), CH2CH=CH2 (10)), respectively, as well as the bridged diruthenium complex [(η5-C9H6)(H3CH2C)CHCH(CH2CH3)(η5-C9H6)][Ru(CO)(μ-CO)]2 (11). These complexes have been characterized by elemental analysis, IR, and 1H NMR spectroscopy. The molecular structures of 6, 9, 10 and 11 were determined by X-ray diffraction analysis. CCDC: 937499, 6; 972340, 9; 944111, 10; 970734, 11.
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