Citation: JIANG Shao-Feng, YAO Qian-Ru, GAO Bi-Fen, CHEN Yi-Lin, LIN Bi-Zhou. Preparation of Mesoporous CdS-Pillared Titanoniobate Nanohybrids and Their Photocatalytic Water-Splitting Activity for Hydrogen Generation[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 514-520. doi: 10.11862/CJIC.2015.077
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Mesoporous CdS-pillared titanoniobate nanohybrids were successfully prepared via an exfoliation-restacking route. It was found that as-prepared CdS-TiNbO5 nanohybrids have an interlayer spacing of 1.19 nm and high specific surface areas of about 93 m2·g-1. The nanohybrids showed a remarkable photocatalytic hydrogen-evolution activity in water splitting. When the molar ratio of CdS and titanoniobate nanosheets was equal to 1:2, the H2-evolution rate reached 231 and 184 μmol·h-1·g-1 under irradiation of 300 W Xe lamp and visible light, which is 8.6 and 9.7 times as high as the blank CdS. The improvement of photocatalytic activity is predominantly ascribed to the enlarged specific surface area and the effective spatial separation of photogenerated carriers between the host and guest.
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-
[1]
[1] Fujishima A. Nature, 1972,238:37-38
-
[2]
[2] Chen X B, Shen S H, Guo L J, et al. Chem. Rev., 2010,110: 6503-6570
-
[3]
[3] Maeda K, Domen K. J. Phys. Chem. Lett., 2010,1:2655-2661
-
[4]
[4] Teets T S, Nocera D G. Chem. Commun., 2011,47:9268-9274
-
[5]
[5] Fan W Q, Zhang Q H, Wang Y. Phys. Chem. Chem. Phys., 2013,15:2632-2649
-
[6]
[6] Kudo A, Miseki Y. Chem. Soc. Rev., 2009,38:253-278
-
[7]
[7] Takagaki A, Tagusagawa C, Hayashi S, et al. Energy Environ. Sci., 2010,3:82-93
-
[8]
[8] Inoue K, Suzuki S, Nagai M. J. Electroceram, 2008,24:110-114
-
[9]
[9] Fan X R, Lin B Zh, Liu H, et al. Int. J. Hydrogen Energy, 2013,38:832-839
-
[10]
[10] Zhang L H, Hu C H, Zhang J F, et al. Chem. Commun., 2013,49:7507-7509
-
[11]
[11] Zhai Z, Huang Y C, Xu L, et al. Nano Res., 2011,4:635-647
-
[12]
[12] Lin H Y, Chang Y S. Int. J. Hydrogen Energy, 2014,39: 3118-3126
-
[13]
[13] Pergentino O, de Brito M M, Andrade H M C, et al. J. Catal., 2014,2014:1-8
-
[14]
[14] Fu J, Chang B B, Tian Y L, et al. J. Mater. Chem. A, 2013, 1:3083-3090
-
[15]
[15] Kar A, Kundu S, Patra A. RSC Adv., 2012,2:10222-10230
-
[16]
[16] ZHANG Yu(张宇), ZHANG Jun-Xiang(张俊祥), FU De-Gang(付德刚), et al. Chin. J. Inorg. Mater.(无机材料学报), 1999,15(5):595-600
-
[17]
[17] Zirak M, Akhavan O, Moradlou O, et al. J. Alloys Compd., 2014,590:507-513
-
[18]
[18] Zhai Z, Hu C H, Yang X Y, et al. J. Mater. Chem., 2012, 22:19122-19131
-
[19]
[19] Zhai Z, Yang X Y, Xu L, et al. Nanoscale, 2012,4:547-556
-
[20]
[20] Zhu B L, Lin B Z, Zhou Y, et al. J. Mater. Chem. A, 2014, 2:3819-3827
-
[21]
[21] Nan Z, Zhang Y H, Pan X Y, et al. J. Phys. Chem. C, 2011, 115:23501-23511
-
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