Citation: LIU Hai-Rui, FANG Li-Yu, JIA Wei, JIA Hu-Sheng. Fabrication of ZnS Nanoparticles with Enhanced Photocatalytic Activity by Hydrothermal Method[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 459-464. doi: 10.11862/CJIC.2015.074 shu

Fabrication of ZnS Nanoparticles with Enhanced Photocatalytic Activity by Hydrothermal Method

LIU Hai-Rui ^1,2,, ,
FANG Li-Yu ² ,
JIA Wei ² ,
JIA Hu-Sheng ²

1.
1 College of Physics and Electronics Engineering, Henan Normal University, Xinxiang, Henan 453007, China;
2.
2 College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: LIU Hai-Rui,
Received Date: 19 June 2014
Available Online: 5 January 2015
Fund Project: 国家自然科学基金(NO.50432030、U1304110)资助项目。 (NO.50432030、U1304110)

Under the role of CTAB, different size ZnS spherical-like particles were fabricated by hydrothermal method. The crystal structure, morphology, composition and optical property of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), X-ray energy spectrum (EDS), UV-Vis absorption spectrum and photoluminescence spectrum (PL). Photocatalytic activities were evaluated by degradation of MB solution. The results show that ZnS nanoparticles were formed by aggregation of crystal nucleus under the role of CTAB. With the increase of reaction time, the size of ZnS particles increased to 500 nm, however, the crystal structure of product has no change. With the increase of particle size, the UV-Vis absorption peak of samples shifted from 418 to 362 nm and the PL intensity further increased. Finally, the photocatalytic activity presented that fabricated ZnS nanoparticles with reaction time 12 h showed best photcatalytic performance.
- ZnS;spherical structure;hydrothermal method;photocatalysis
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