Citation: JIN Chao, WANG Yin-Ge, QIAN Hui-Fen, HUANG Wei. A Cu(Ⅱ) Complex with2,9-Dithienyl-1,10-phenanthroline-5,6-dione Ligand with Large Steric Hindrance[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 413-419. doi: 10.11862/CJIC.2015.054
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1,10-Phenanthroline-5,6-dione based molecules (1 and 2), extended by two thiophene rings at 2 and 9 positions, have been designed and prepared successfully. It is interesting to mention that the study of coordination chemistry of this large steric ligand 2 with some transition-metal ions reveals that only a Cu(Ⅱ) complex 3·H2Ocan be yielded. The conformation of ligand 2 undergoes great alteration after Cu(Ⅱ) ion complexation, where the dihedral angles between the central 1,10-phenanthroline-5,6-dione and its neighboring two thiophene rings are significantly increased from 1.9(2)°/5.6(2)° in 2 and 5.2(6)°/6.5(6)° in 2·CHCl3 to 25.3(3)°/27.2(3)° and 34.9(3)°/38.2(3)° in 3·H2O in order to meet the geometric requirement of four-coordinate Cu(Ⅱ) centre. CCDC: 1013452, 2; 1013453, 2·CHCl3; 1013454, 3·H2O.
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-
[1]
[1] Carlin R L, Dejongh L J. Chem. Rev., 1986,86:659-680
-
[2]
[2] Bauerle P, Mullen K. Electronic Materials. Weinheim: Wiley-VCH, 1998:105-197
-
[3]
[3] Ma Z, Jacobsen F E, Giedroc D P. Chem. Rev., 2009,109: 4644-4681
-
[4]
[4] Torre G, Vazquez P, Agullo-Lopez F, et al. Chem. Rev., 2004, 104:3723-3750
-
[5]
[5] Campbell C T, Sellers J R V. Chem. Rev., 2013,113:4106-4135
-
[6]
[6] Brandt W W, Dwyer F P, Gyarfas E D. Chem. Rev., 1954, 54:959-1017
-
[7]
[7] Sivula K, Luscombe C K, Thompson B C, et al. J. Am. Chem. Soc., 2006,128:13988-13989
-
[8]
[8] Narutaki M, Takimiya K, Otsubo T, et al. J. Org. Chem., 2006,71:1761-1768
-
[9]
[9] Huang W, Masuda G, Maeda S, et al. Chem. Eur. J., 2006,12: 607-619
-
[10]
[10] Huang W, Masuda G, Maeda S, et al. Inorg. Chem., 2008, 47:468-480
-
[11]
[11] Margapoti E, Shukla V, Valore A, et al. J. Phys. Chem. C., 2009,113:12517-12522
-
[12]
[12] Ammann M, Bauerle P. Org. Biomol. Chem., 2005,3:4143-4152
-
[13]
[13] Vidal P L, Blohorn B D, Bidan G, et al. Chem. Eur. J., 2000,6:1663-1673
-
[14]
[14] Hu B, Fu S J, Xu F, et al. J. Org. Chem., 2011,76:4444-4456
-
[15]
[15] Xu F, Peng Y X, Hu B. CrystEngComm, 2012,14:8023-8032
-
[16]
[16] Huang W, Tanaka H, Ogawa T. J. Phys. Chem. C, 2008, 112:11513-11526
-
[17]
[17] Wang L, You W, Huang W, et al. Inorg. Chem., 2009,48: 4295-4305
-
[18]
[18] Huang W, Wang L, Tanaka H, et al. Eur. J. Inorg. Chem., 2009:1321-1331
-
[19]
[19] Zhang B, Cao K S, Xu Z A, et al. Eur. J. Inorg. Chem., 2012:3844-3851
-
[20]
[20] Wang X X, Tao T, Geng J, et al. Chem. Asian J., 2014,9: 514-525
-
[21]
[21] Peng Y X, Tao T, Wang X X, et al. Chem. Asian J., 2014,9: 3593-3603
-
[22]
[22] SAINT, Version 6.02. Bruker AXS, Inc., Madisson, WI, 2001.
-
[23]
[23] Sheldrick G M. SHELXTL, Version 6.10, Bruker Analytical X-ray Systems, Madison, WI, 2001.
-
[24]
[24] Brandenburg K. Diamond Version 3.2c, Crystal and Molecular Structure Visualization, Crystal Impact, K. Brandenburg & H. Putz Gbr, Bonn, Germany, 2009.
-
[25]
[25] Mellace M G, Fagalde F, Katz N E, et al. Inorg. Chem., 2004,43:1100-1106
-
[26]
[26] Ashby E C. J. Am. Chem. Soc., 1997,119:9085-9086
-
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