Citation: FAN Fang-Lu, JING Jin-Qiu, CHEN Xue-Mei. Synthesis, Crystal Structure and Spectroscopic Property of a Benzothiazole-Based Fluorescent Probe for Cu²⁺[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 548-554. doi: 10.11862/CJIC.2015.026 shu

Synthesis, Crystal Structure and Spectroscopic Property of a Benzothiazole-Based Fluorescent Probe for Cu²⁺

1.
1 School of Materials and metallurgy, Hubei Polytechnic University, Huangshi, Hubei 435003, China;
2.
2 College of Chemistry and Chemical Engineering, Hubei Polytechnic University, Huangshi, Hubei 435003, China

Corresponding author: FAN Fang-Lu,
Received Date: 19 September 2014
Available Online: 21 October 2014
Fund Project: 国家自然科学基金(No.51173060)资助。 (No.51173060)

A benzothiazole-based fluorescent probe N-(4-(benzo[d]thiazol-2-yl)phenyl)-2-((2-hydroxyethyl) (pyridin-2-ylmethyl)amino)acetamide (FL) has been synthesized and characterized, and its recognition properties towards various metal ions have been studied by spectrometry. The results showed that FL was highly sensitive and selective to Cu²⁺, and other metal ions did not interfere with its recognition for Cu²⁺. The stoichiometry of the complex formation of FL with Cu²⁺ was determined to be 1:1, and the fluorescence intensity of FL varied almost linearly versus the concentration of Cu²⁺ (3.8~9.6 μmol·L^-1). FL can also be applied to detect Cu²⁺ in different water samples such as tap and lake water.
- benzothiazole;crystal structure;Cu²⁺;fluorescent probe
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Spectroscopic Property of a Benzothiazole-Based Fluorescent Probe for Cu2+

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and Spectroscopic Property of a Benzothiazole-Based Fluorescent Probe for Cu²⁺