Citation: HUANG Yan-Ping, ZHANG Xiao, LIU Lei, ZHANG Nan-Xi, XU Xian-Zhu. Synthesis and Crystal Structure of Transition Metal Coordination Compounds with Triethylenediamine Ligand and Their Florescence Properties Studies[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1001-1008. doi: 10.11862/CJIC.2014.186
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Aseries of transition metal coordination compounds based on the ligand, triethylenediamine(dabco), [CdCl3H(dabco)2] (1), [CoCl3Hdabco] (2), [NiCl2(H2O)3Hdabco]Cl (3), [CuCl3H(dabco)2]Cl·H2O (4) have been prepared and characterized by elemental analyses, IRspectra, thermogravimety and single crystal X-Ray diffraction structure analyses. Compound 1 displays an one-dimensional straight chain via the hydrogen bonding interactions. Compound 2 possesses the left helix molecular structure. Compound 3 possesses the right helix molecular structure and compound 4 exhibits a two-dimensional molecular sheet with grids. Compounds 1 to 4 show intensive photoluminescence.
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