Citation: LI Dong-Lin, MA Shou-Long, LI Yan, XIE Rong, TIAN Miao, FAN Xiao-Yong, GOU Lei, SHI Yong-Xin, YONG Hong-Tuan-Hua, HAO Li-Min. EDTA Assisted Synthesis and Electrochemical Performance of Li₂MnSiO₄/C Nanocomposite as a Cathode Material for Lithium Ion Btteries[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1056-1062. doi: 10.11862/CJIC.2014.167 shu

EDTA Assisted Synthesis and Electrochemical Performance of Li₂MnSiO₄/C Nanocomposite as a Cathode Material for Lithium Ion Btteries

1.
Energy Materials & Devices Group, School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China

Received Date: 18 August 2013
Available Online: 25 February 2014
Fund Project: 国家自然科学基金(No.21073021，20903016，21103013)；教育部高等学校科学技术重大项目培育资金项目(No.708084) (No.21073021，20903016，21103013)；教育部高等学校科学技术重大项目培育资金项目(No.708084)中央高校基本科研业务费专项资金(No.CHD2010ZD008，CHD2011ZD007)资助项目。 (No.CHD2010ZD008，CHD2011ZD007)

Li₂MnSiO₄/C nanospheres were prepared by combining the sol-gel and solvothermal processing using ethylene diamine tetraacetic acid (EDTA) as a chelating agent. After calcined under Ar atmosphere at 700 ℃, the (Li, Mn, Si)precursor complexed by EDTAtransformed into Li₂MnSiO₄/C nanocomposite particles approximately 50 nm in diameter. The initial charge and discharge specific capacities of the sample are 223 and 140 mAh·g^-1 at a current density of 33 mA·g^-1 (0.1C), respectively, and fifth discharge specific capacity can be achieved 138 mAh·g^-1. The discharge specific capacity still is stabilized at around 80 mAh·g^-1 at a current density of 66 mA·g^-1 (0.2C) after 20 cycles. These results indicate that EDTAcan prevent secondary crystalline phase of forming during calcinations. Such well-dispersed nano-powder exhibits improved cycleability for Li₂MnSiO₄ cathode.
- EDTA;Complexation;Li₂MnSiO₄;Cathode;Lithium-ion battery
1. [1]
  [1] Nytén A, Abouimrane A, Armand M, et al. Electrochem. Commun., 2005, 7(2):156-160
2. [2]
  [2] ZUO Peng-Jian(左朋建), WANG Zhen-Bo(王振波), YIN Ge-Ping(尹鸽平), et al. Materials Review(材料导报), 2009, 23 (6):28-31
3. [3]
  [3] Wu X Z, Jiang X, Huo Q S, et al. Electrochim. Acta, 2012, 80:50-55
4. [4]
  [4] Bai J Y, Gong Z J, Lv D P, et al. J. Mater. Chem., 2012, 22: 12128-12132
5. [5]
  [5] Fan X Y, Li Y, Wang J J, et al. J. Alloys Compd., 2010, 493: 77-80
6. [6]
  [6] Dompablo Arroyo-de M E, Armand M, Tarascon J M, et al. Electrochem. Commun., 2006, 8:1292-1294
7. [7]
  [7] Islam S M. Phil. Trans. R. Soc. A, 2010, 368:3255-3267
8. [8]
  [8] Dominko R. J. Power Sources, 2008, 184:462-468
9. [9]
  [9] Dominko R, Bele M, GaberšČek M, et al. Electrochem Commun., 2006, 8:217-222
10. [10]
  [10] Shao B, Abe Y, Taniguchi I. Powder Technol., 2013, 235:1-8
11. [11]
  [11] Li Y X, Gong Z L, Yang Y. J. Power Sources, 2007, 174(2): 528-532
12. [12]
  [12] Liu S, Xu J, Li D Z, et al. J. Power Sources, 2013, 232:258-263
13. [13]
  [13] Liu J, Xu H Y, Jiang X L, et al. J. Power Sources, 2013, 231:39-43
14. [14]
  [14] Aravindan V, Ravi S, Kim W S, et al. J. Colloid Interface Sci., 2011, 355:472-477
15. [15]
  [15] WEI Yi(魏怡), WANG Li-Juan(王利娟), YAN Ji(闫继), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2011, 27(11): 2587-2592
16. [16]
  [16] Aricoa S, Bruce P, Scrosati B, et al. Nat. Mater., 2005, 4:366-377
17. [17]
  [17] Li D L, Kong L B, Zhang L Y, et al. J. Non-Cryst. Solids, 2000, 271:45-55
18. [18]
  [18] LI Dong-Lin(李东林), TIAN Miao(田苗), LI Qian(李倩), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 29(9): 1903-1908
19. [19]
  [19] Li D L, Tian M, Xie R, et al. J. Alloys Compd., 2014, 582: 88-95
20. [20]
  [20] Wang J, Li D L, Fan X Y, et al. J. Alloys Compd., 2012, 516:33-38
21. [21]
  [21] JIANG Wei(姜炜), LI Feng-Sheng(李凤生), CHEN Ling-Yun(陈令允), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2005, 21(2):182-186
22. [22]
  [22] XI Guo-Xi(席国喜), LIU Yu-Min(刘玉民), QI Shi-Mei(戚世梅), et al. Bull. Chin. Ceram. Soc.(硅酸盐通报), 2009, 28 (1):194-199
23. [23]
  [23] ZHU Chen-Fei(朱承飞), XUE Jin-Hua(薛金花), WANG Li (王李), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010, 26(7):1165-1170
24. [24]
  [24] Di Noto V, Münchow V, Vittadello M, et al. Macromol. Chem. Phys., 2002, 203:1211-1216
25. [25]
  [25] Li D Y, Zhang L Y, Yao X. J. Non-Cryst. Solids, 2008, 354: 1774-1778
26. [26]
  [26] Dompablo Arroyo y de M E, Amador U, Gallardo-Amores J M, et al. J. Power Sources, 2009, 189:638-642
27. [27]
  [27] Li D L, Zhou H S, Honma I. Chem. Commun., 2005, 41: 5187-5189
28. [28]
  [28] Li D L, Zhou H S, Honma I. Nat. Mater., 2004, 3:65-72
29. [29]
  [29] Li D L, Tian M, Xie R, et al. Nanoscale, 2014, 6:3302-3308
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
3. [3]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
4. [4]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
5. [5]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
6. [6]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
7. [7]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
8. [8]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
9. [9]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
10. [10]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
11. [11]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
12. [12]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
13. [13]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
14. [14]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
15. [15]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
16. [16]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
17. [17]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
18. [18]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
19. [19]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
20. [20]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(266)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

EDTA Assisted Synthesis and Electrochemical Performance of Li2MnSiO4/C Nanocomposite as a Cathode Material for Lithium Ion Btteries

Metrics

通讯作者: 陈斌, bchen63@163.com

EDTA Assisted Synthesis and Electrochemical Performance of Li₂MnSiO₄/C Nanocomposite as a Cathode Material for Lithium Ion Btteries