Citation: GUAN Lei, GAO Wei, ZHANG Zu-Kang, WANG Ying. Synthesis, Crystal Structures and Luminescent Properties of Two Nickel Mononuclear Complexes Containing N-donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1187-1194. doi: 10.11862/CJIC.2014.139 shu

Synthesis, Crystal Structures and Luminescent Properties of Two Nickel Mononuclear Complexes Containing N-donor Ligands

1.
1 School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China;

Received Date: 16 September 2013
Available Online: 25 October 2013

The synthesis of the two Ni(Ⅱ) mononuclear complexes containing N-donor ligands [Ni(phen)₂(H₂O)₂](1,6-nds)·2H₂O (1) and [Ni(phen)₃](1,6-nds)·10H₂O (2) (1,6-nds=1,6-naphthalene-disulfonate anion, phen=1,10-phenanthroline) was conducted in water by the reflux method. For the complex 1, the nickel ion coordinates with two 1,10-phenanthroline ligands and two water molecules, respectively, forming the [Ni(phen)₂(H₂O)₂]²⁺ cation, and the two uncoordinated water molecules connect to the [Ni(phen)₂(H₂O)₂]²⁺ cations and 1,6-nds anions to form a two-dimensional layered structure via the hydrogen bonds. For the complex 2, the nickel ion coordinates with three 1,10-phenanthroline ligands to form the [Ni(phen)₃]²⁺ cation. There are abundant hydrogen bonds between free water molecules and 1,6-nds anions, leading to a three-dimensional network structure. In the two complexes, the 1,6-nds anions don't coordinate with the nickel ions, only balance the charges. The complexes exhibit strong luminescence with emission maximum at 443 and 438 nm at room temperature, respectively.
- nickel complex;luminescent property;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142