Citation: CHEN Li-Juan, CHEN Xia, HOU Qin-Biao, YANG Ming-Xing, LIN Shen. Two Coordination Polymers with 3D stp Topology {[Ln2(pda)3(H2O)2]·2H2O}n (Ln=Nd, La)[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 786-792. doi: 10.11862/CJIC.2014.124
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Two isomorphous coordination polymers, {[Ln2(pda)3(H2O)2)·2H2O}n (Ln=Nd(1), La(2)), have been hydrothermally synthesized by reaction of rare-earth oxides and o-phenylenediacetic acid (H2pda). The two compounds have been characterized by X-ray single-crystal diffraction, infrared spectroscopy, fluorescence spectroscopy and TG analysis. Crystal structure determination shows that both two compounds crystallized in monoclinic, space group C2/c. Crystallographic parameters for complex 1, a=2.62906(18) nm, b=1.61172(11) nm, c=0.78327(5) nm, β=93.173(5)°, V=3.3139(4) nm3, Z=4, F(000)=1840, μ=3.173 mm-1, Dc=1.878 g·cm-3, R1=0.0226, wR2=0.0609; complex 2, a=2.6271(14) nm, b=1.6149(8) nm, c=0.7966(4) nm, β=92.850(9)°, V=3.3139(4) nm3, Z=4, F(000)=1816, μ=2.570 mm-1, Dc=1.823 g·cm-3, R1=0.0466, wR2=0.1416. In the two compounds, neighboring lanthanide ions are connected by o-phenylenediacetate to form 3D networks with stp topology. TG and FL analysis indicate that both compounds have good thermal stability and compound 2 exhibits emission in the solid state at room temperature.
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-
[1]
[1] James S L. Chem. Soc. Rev., 2003, 32:276-288
-
[2]
[2] Bo Q B, Sun G X, Geng D L. Inorg. Chem., 2009, 49:561-571
-
[3]
[3] Fischer R A, Woll C. Angew. Chem. Int. Ed., 2008, 47(43): 8164-8168
-
[4]
[4] Huang, Y G, Jiang F L, et al. J. Solid State Chem., 2009, 182, 215-222
-
[5]
[5] Reineke T M, Eddaoudi M, OKeeffe M, et al. Angew. Chem. Int. Ed., 1999, 38(17):2590-2594
-
[6]
[6] WANG Chun-Yan(王春燕), WU Xiao-Shuo(吴小说), LI Xia (李夏). Chinese J. Inorg. Chem. (无机化学学报), 2008, 24 (5):781-784
-
[7]
[7] Soares-Santos P C R, Cunha-Silva L, Paz F A A. et al. Cryst. Growth Des., 2008, 8(7):2505-2516
-
[8]
[8] Zhang Z H, Shen Z L, Okamura T, et al. Cryst. Growth Des., 2005, 5(3):1191-1197
-
[9]
[9] LIU Jing(刘静), WANG Min(王敏), ZHANG Zhen-Wei (张振伟), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(1):50-54
-
[10]
[10] Yuan G, Shao K Z, Du D Y, et al. CrystEngComm, 2012, 14: 1865-1873
-
[11]
[11] Chen L J, Su J B, Huang R B, et al. Dalton Trans., 2011, 40:9731-9736
-
[12]
[12] He X, Lu X P, Li M X, et al. Cryst. Growth Des., 2013, 13: 1649-1654
-
[13]
[13] Chen L J, Wu X Y, Zhai Q G, et al. Inorg. Chem. Commun., 2007, 10:1457-1460
-
[14]
[14] Zhang F W, Li Z F, Ge T Z, et al. Inorg. Chem., 2010, 49: 3776-3788
-
[15]
[15] LIN Pei-Xi(林培喜), KANG Xin-Ping(康新平), AN Zhe (安哲). Chinese J. Inorg. Chem. (无机化学学报), 2011, 27 (7):1446-1450
-
[16]
[16] LU Wen-Guan(卢文贯), LIU Hong-Wen(刘宏文). Chinese J. Inorg. Chem. (无机化学学报), 2010, 26(8):1450-1456
-
[17]
[17] LUAN Guo-You(栾国有), WANG Ming-Hui(王明辉), WANG En-Bo(王恩波), et al. Chinese J. Molecular Science (分子科学通报), 2001, 17(2):121-123
-
[18]
[18] Rigaku Molecular Structure Corporations, TEXSAN, Version 1.10. MSC. 9009 New Trails Drive, The Woodlands, TX77381-5209, U.S.A. 1999.
-
[19]
[19] Sheldrick G M. SHELX-97 Program for Refinement of Crystal Structure. University of Göttingen, Germany, 1997.
-
[20]
[20] Chen X M, Liu G F. Chem. Eur. J., 2002, 20:4811-4817
-
[1]
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