Citation: CHEN Peng, DU Lin, ZHOU Jie, QIAO Yong-Feng, LI Bin, ZHAO Qi-Hua. Four Complexs with Triazine Derivative and Terephthalate：Synthesis, Structures, and Luminescent, Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1038-1044. doi: 10.11862/CJIC.2014.115 shu

Four Complexs with Triazine Derivative and Terephthalate：Synthesis, Structures, and Luminescent, Magnetic Properties

CHEN Peng ^1,2 ,
DU Lin ¹ ,
ZHOU Jie ¹ ,
QIAO Yong-Feng ¹ ,
LI Bin ¹ ,
ZHAO Qi-Hua ¹

1.
1 Department Chemistry, Yunnan University, Kunming 650000, China;

Received Date: 5 June 2013
Available Online: 11 November 2013
Fund Project: 国家自然科学基金(No.21371151) (No.21371151)云南省教育厅项目(NO.2011Y111)资助项目。 (NO.2011Y111)

Four polymers ([Mn(H₂O)(PTZDA)(BDC)]_n(1), [Co(H₂O)(PTZDA)(BDC)]_n(2), [Zn(H₂O)(PTZDA)(BDC)]_n(3), [Cd(H₂O)(PTZDA)(BDC)]_n(4) (PTZDA=6-(pyridyl-2-yl)-1,3,5-triazine-2,4-diamine, BDC=terephthalate) have been synthesized by hydrothermal reactions and structurally charecaterized by single crystal X-ray diffraction, elemental analysis, IR, TG and PXRD. Structural analysis reveals that the metal ions of compounds 1~4 are bridged by two carboxyl group from, terephthalate acid and are chelated by two nitrogen atoms from PTZD Aligand to form a one dimensional chain. These chains are further extended to 3D supramolecular structure by hydrogen bonds. The magnetic properties of compound 1~2 have been studied, indicating that they exist weak anti-ferromagnetism. Luminescent properties of compounds 3~4 indicates complex 3 and 4 possessing quality of photo-luminescent, which is assigned to the ligands.
- triazine derivative;terephthalate;crystal structure;anti-ferromagnetism;luminescent property
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