Citation: FENG Chao, MO Zun-Li, GOU Hao, ZHANG Chun. Preparation and Fluorescence Property of Europium Complex Nanocrystals Growing on Graphene Oxide[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 677-682. doi: 10.11862/CJIC.2014.105 shu

Preparation and Fluorescence Property of Europium Complex Nanocrystals Growing on Graphene Oxide

1.
Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

Received Date: 19 June 2013
Available Online: 31 October 2013
Fund Project: 国家自然科学基金(No.51262027)资助项目。 (No.51262027)

In this study, Eu(Ⅲ) complex nanocrystals had grown on graphene oxide (GO) by π-π stacking. Fourier transform infrared spectroscopy (FTIR), transmission electron morphology (TEM) and X-ray diffraction (XRD) were used to demonstrate the successful growth of Eu(Ⅲ) complex nanocrystals on GO surface. Investigations using fluorescence spectroscopy proved the fluorescence property of the composite and the fluorescence quenching concentration of Eu³⁺ was 18wt%. Thermogravimetric analysis(TGA) showed that the thermal stability of the composite had been remarkably improved comparing with pure complex.
- graphene oxide;nanocrystal;complex;composite
1. [1]
  [1] Chen D, Feng H B, Li J H. Chem. Rev., 2012,112:6027-6053
2. [2]
  [2] Mkhoyan K A, Contryman A W, Silcox J, et al. Nano Lett., 2009,9(3):1058-1063
3. [3]
  [3] Lu N, Yin D, Li Z Y, et al. J. Phys. Chem. C, 2011,115: 11991-11995
4. [4]
  [4] Wang H L, Casalongue H S, Liang Y Y, et al. J. Am. Chem. Soc., 2010,132:7472-7477
5. [5]
  [5] Zhou Y, Bao Q L, Tang L A L, et al. Chem. Mater., 2009,21(13):2950-2956
6. [6]
  [6] Liu H T, Ryu S, Chen Z Y, et al. J. Am. Chem. Soc., 2009, 131:17099-17101
7. [7]
  [7] Long R L, English N J, Prezhdo O V. J. Am. Chem. Soc., 2012,134:14238-14248
8. [8]
  [8] Ran C X, Wang M Q, Gao W Y, et al. J. Phys. Chem. C, 2012,116:23053-23060
9. [9]
  [9] Liu Z B, Xu Y F, Zhang X Y, et al. J. Phys. Chem. B, 2009,113(29):9681-9686
10. [10]
  [10] Exarhos A L, Turk M E, Kikkawa J M. Nano Lett., 2013,13: 344-349
11. [11]
  [11] Cao Y X, Yang T, Feng J C, et al. Carbon, 2011,49:1502-1507
12. [12]
  [12] Valta T, Puputti E M, Hyppnen I, et al. Anal. Chem., 2012, 84:7708-7712
13. [13]
  [13] Ratnakar S J, Viswanathan S, Kovacs Z, et al. J. Am. Chem. Soc., 2012,134:5798-5800
14. [14]
  [14] Andres J, Chauvin A S. Inorg. Chem., 2011,50:10082-10090
15. [15]
  [15] Zhang L, Wang Y J, Ye Z Q, et al. Bioconjugate Chem., 2012,23:1244-1251
16. [16]
  [16] Gupta B K, Thanikaivelan P, Narayanan T N, et al. Nano Lett., 2011,11:5227-5233
17. [17]
  [17] Hummers W S Jr, Offeman R E. J. Am. Chem. Soc., 1958, 80:1339
18. [18]
  [18] Li S W, Zhong X, Yang H L, et al. Carbon, 2011,49:4239-4245
19. [19]
  [19] Zedan A F, Sappal S, Moussa S, et al. J. Phys. Chem. C, 2010, 114:19920-19927
20. [20]
  [20] Wang Y B, Kurunthu D, Scott G W, et al. J. Phys. Chem. C, 2010,114:4153-4159
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1.
沈阳化工大学材料科学与工程学院沈阳 110142