Citation: ZHAO Yue, ZHAI Ling-Ling, SUN Wei-Yin*. Synthesis, Crystal Structure and Fluorescence Property of Zn(Ⅱ), Cd(Ⅱ)Coordination Polymers with Benzoimidazol-Containing Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 99-105. doi: 10.11862/CJIC.2014.081 shu

Synthesis, Crystal Structure and Fluorescence Property of Zn(Ⅱ), Cd(Ⅱ)Coordination Polymers with Benzoimidazol-Containing Ligand

1.
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 3 September 2013
Available Online: 19 November 2013
Fund Project:

Two new coordination polymers [Zn(L)(m-BDC)] (1) and [Cd(L)(CCA)]·2H₂O (2) were synthesized by solvothermal method using 3,5-di(1H-benzoimidazol-1-yl)pyridine (L), isophthalic acid (m-H₂BDC), 4-(2-carbox-yvinyl)benzoic acid (H₂CCA). And the complexes were characterized by FT-IR, elemental analysis, thermogravimetric analysis (TGA) and power X-ray diffraction (PXRD), meanwhile the crystal structures and fluorescence properties of the complexes have been studied. In complex 1, the ligand Lconnects the metal atoms to give a 1Dchain structure, and the m-BDC^2- coordinates with metal atom to form a M₂(m-BDC)₂ unit (M=metal). Moreover, the adjacent 1D chains are linked by the M₂(m-BDC)₂ to produce a 2D network structure. In complex 2, the ligand joins the metal atoms to generate a 1D chain like that in 1. However, the carboxylate ligand coordinates with metal atoms to form a 1D chain, and two kinds of the 1D chains crosslink each other to produce a 2D structure.
- coordination polymers;fluorescence property;crystal structure,
1. [1]
  [1] Meot-Ner M. Chem. Rev., 2005, 105:213-284
2. [2]
  [2] O'Keeffe M, Yaghi O M. Chem. Rev., 2012, 112:675-702
3. [3]
  [3] LI Zheng(李正), ZHAO Yue(赵越), WANG Peng(王鹏), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28:1469-1476
4. [4]
  [4] Gao Q, Xie Y B, Li J R, et al. Cryst. Growth Des., 2012, 12: 281-288
5. [5]
  [5] Herm Z R, Swisher J A, Smit B, et al. J. Am. Chem. Soc., 2011, 133:5664-5667
6. [6]
  [6] Pan M, Lin X M, Li G B, et al. Coord. Chem. Rev., 2011, 255:1921-1936
7. [7]
  [7] Swiegers G F, Malefetse T J. Chem. Rev., 2000, 100:3483-3537
8. [8]
  [8] Luo L, Zhao Y, Lu Y, et al. Polyhedron, 2012, 38:88-96
9. [9]
  [9] Zhao Y, Lv M F, Fan J, et al. Inorg. Chim. Acta, 2011, 377: 138-143
10. [10]
  [10] Chen M, Chen M S, Okamura T, et al. CrystEngComm, 2011, 13:3801-3810
11. [11]
  [11] Yang W, Schmider H, Wu Q, et al. Inorg. Chem., 2000, 39: 2397-2404
12. [12]
  [12] Lin W, Wang Z, Ma L. J. Am. Chem. Soc., 1999, 121:11249-11250
13. [13]
  [13] Software Packages SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison, WI, 1996.
14. [14]
  [14] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
15. [15]
  [15] Su Z, Xu J, Fan J, et al. Cryst. Growth Des., 2009, 9:2801-2811
16. [16]
  [16] Zhu H F, Fan J, Okamura T, et al. Cryst. Growth Des., 2005, 5:289-294
17. [17]
  [17] Chen S S, Bai Z S, Fan J, et al. CrystEngComm, 2010, 12: 3091-3104
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沈阳化工大学材料科学与工程学院沈阳 110142